Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chinese Journal of Catalysis》 2005-05
Add to Favorite Get Latest Update

Deactivation and Regeneration of Amorphous Ru-La-B/ZrO_2 Catalystfor Selective Hydrogenation of Benzene to Cyclohexene

WANG Hui, LIU Zhongyi, SHI Ruijuan, ZHANG Yongna, ZHANG Hongquan, LIU Shouchang~*(Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, China)  
The amorphous Ru-La-B/ZrO_2 catalyst was prepared and used for the selective hydrogenation of benzene to cyclohexene in the pilot plant. Ru-La-B/ZrO_2 showed satisfied activity, selectivity, stability, subside and separate performance. The deactivation reasons for the catalyst running for a long time in the pilot plant were investigated by measuring surface area, pore diameter distribution and ion content in the catalyst as well as in slurry. It was found that the catalyst deactivation was not caused by the plugging of catalyst micropores, decrease in surface area, crystalline grain growth or catalyst poisoning. It was just because that excess Zn~ 2+ and Fe~ 2+ from the reaction slurry were adsorbed on the catalyst. After washing with acid, the activity and selectivity of the catalyst were almost completely recovered. This acid-washing method prolongs the catalyst life and make the catalyst open up a very good prospect in industrialization.
【CateGory Index】: O643.3
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 9 Hits
1 SUN Haijie,GUO Wei,ZHOU Xiaoli,CHEN Zhihao,LIU Zhongyi,LIU Shouchang Department of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;Progress in Ru-Based Amorphous Alloy Catalysts for Selective Hydrogenation of Benzene to Cyclohexene[J];Chinese Journal of Catalysis;2011-01
2 SUN Haijie,ZHANG Xudong,CHEN Zhihao,ZHOU Xiaoli,GUO Wei,LIU Zhongyi,LIU Shouchang Department of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;Monolayer Dispersed Ru-Zn Catalyst and Its Performance in the Selective Hydrogenation of Benzene to Cyclohexene[J];Chinese Journal of Catalysis;2011-02
3 JI Wenjin, HUANG Huimin, DENG Shuhua, ZHENG Yuying,OU Dehua (Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006);A General Review of Amorphous Alloy Catalysts[J];Materials Review;2006-05
4 HUANG Zhen-xu , LIU Zhong-yi, WU Yong-mei , LIU Shou-chang~ 1) ( Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China );Selective Hydrogenation of Benzene to Cyclohexene by a Novel Ru-Zn Catalyst[J];Journal of Molecular Catalysis;2006-03
5 WEN Gao-fei,YANG Zhu-hong,LI Wei,FENG Xin,LU Xiao-hua(College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing,Jiangsu 210009,China);Inhibition of Photocatalytic Activity of Titania Whiskers with Ultraviolet Deposition[J];The Chinese Journal of Process Engineering;2007-06
6 LIU Yan-li,ZHAO Shu-hui,LIU Shou-chang (Department of Chemistry,Zhengzhou University,Zhengzhou 450052,China);Production of Phenol and Cyclohexanone by Selective Hydrogenation of Benzene[J];Henan Chemical Industry;2006-12
7 HUANG Zhen-xu1,LIU Shou-chang2(1.Department of Chemistry,Zhengzhou Teachers College,Zhengzhou 450044,China;2.Department of Chemistry,Zhengzhou University,Zhengzhou 450052,China);Preparation and Characterization of Ru-Fe Catalyst by Precipitation Method for Hydrogenation of Benzene to Cyclohexene[J];Henan Chemical Industry;2009-03
8 LI Ning,MA Qing-feng,LIU Wei,L Yi-hao(College of Chemistry and Bioengineering,Guilin University of Technology,Guilin 541004,Guangxi,China);Study on Catalytical Performance of Supported NiB Amorphous Alloy on Hydrogenation of α-Pinene[J];Fine Chemicals;2010-11
9 HUANG Zhenxu;GAO Hairong;PEI Xianru;LIU Shouchang;Wei Shiqian;Department of Chemistry,Zhengzhou Normal University;Department of Chemistry,Zhengzhou University;Journal Editorial Section,Xuchang University;;Characterization of Ru-Fe/ZrO_2 Catalyst for Hydrogenation of Benzene to Cyclohexene[J];Journal of Henan University of Science & Technology(Natural Science);2014-04
【Citations】
Chinese Journal Full-text Database 3 Hits
1 LIU Shouchang *, LUO Ge, WANG Hairong, XIE Yunlong, YANG Bangju, HAN Minle(Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, China);Study on Operation Conditions for Liquid Phase Selective Hydrogenation of Benzene to Cyclohexene over Ru-M-B/ZrO_2 Catalyst[J];Chinese Journal of Catalysis;2002-04
2 LIU Shou-chang, ZHU Bo-zhong, LUO Ge, WANG Hai-rong, HAN Min-le(Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China);Characterization of Amorphous Ru-M-B/ZrO_2 Catalysts for Partial Hydrogenation of Benzene to Cyclohexene[J];Journal of Molecular Catalysis (China);2002-03
3 Wu Jimin,Yang Yanfeng,Chen Juliang(Nylon 66 Salt Co.Ltd,Shenma Group of China, Pingdingshan 467013);Study on the Causes of Catalyst Inactivation of Benzene Semi-hydrogenation[J];Chemical Industry and Engineering Progress;2003-03
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LIU Shouchang *, LUO Ge, HAN Minle, Li Zhongjun (Institute of Industrial Catalysis, Zhengzhou University, Zhengzhou 450052, China);Characterization of the Catalyst Prepared by Impregnation for Selective Hydrogenation of Benzene to Cyclohexene[J];Chinese Journal of Catalysis;2001-06
2 LIU Shouchang *, LUO Ge, WANG Hairong, XIE Yunlong, YANG Bangju, HAN Minle(Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, China);Study on Operation Conditions for Liquid Phase Selective Hydrogenation of Benzene to Cyclohexene over Ru-M-B/ZrO_2 Catalyst[J];Chinese Journal of Catalysis;2002-04
3 WU Yuedong, GUO Haibing, WAN Ying, WANG Minghui, LI Hexing *(Department of Chemistry, Shanghai Normal University, Shanghai 200234, China);Hydrogenation of Glucose to Sorbitol over Amorphous Ru-B/SiO_2 Catalyst in Liquid Phase[J];Chinese Journal of Catalysis;2004-07
4 HE Huimin,YUAN Peiqing,MA Yueming,CHENG Zhenmin,YUAN Weikang State Key Laboratory of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China;Theoretical and Experimental Study on the Partial Hydrogenation of Benzene over Ru-Zn/ZrO_2 Catalyst[J];Chinese Journal of Catalysis;2009-04
5 SUN Haijie,GUO Wei,ZHOU Xiaoli,CHEN Zhihao,LIU Zhongyi,LIU Shouchang Department of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;Progress in Ru-Based Amorphous Alloy Catalysts for Selective Hydrogenation of Benzene to Cyclohexene[J];Chinese Journal of Catalysis;2011-01
6 SUN Haijie,ZHANG Xudong,CHEN Zhihao,ZHOU Xiaoli,GUO Wei,LIU Zhongyi,LIU Shouchang Department of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;Monolayer Dispersed Ru-Zn Catalyst and Its Performance in the Selective Hydrogenation of Benzene to Cyclohexene[J];Chinese Journal of Catalysis;2011-02
7 SUN Haijie,PAN Yajie,WANG Hongxia,DONG Yingying,LIU Zhongyi *,LIU Shouchang Department of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;Selective Hydrogenation of Benzene to Cyclohexene over a Ru-Zn Catalyst with Diethanolamine as an Additive[J];Chinese Journal of Catalysis;2012-04
8 WANG Jian qiang, XIE Song hai, CHEN Hai ying, HU Jian guo, FAN Kang nian, QIAO Ming hua (Molecular Catalysis & Innovative Material Laboratory, Department of Chemistry, Fudan University, Shanghai 200433, China);The Preparation and Catalytic Behavior of Ru/ZrO_2·xH_2O in Benzene Selective Hydrogenation[J];Journal of Fudan University;2002-04
9 Liang Hongyu, Zhang Lianhong, Jiang Heng (Department of Applied Chemistry, Fushun Petroleum Institute, Liaoning Fushun 113001,China);The Research Development of Hydrogenation of Benzene to Cyclohexene[J];JOURNAL OF FUSHUN PETROLEUM INSTITUTE;2000-02
10 LIU Shou-chang, ZHU Bo-zhong, LUO Ge, WANG Hai-rong, HAN Min-le(Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China);Characterization of Amorphous Ru-M-B/ZrO_2 Catalysts for Partial Hydrogenation of Benzene to Cyclohexene[J];Journal of Molecular Catalysis (China);2002-03
China Proceedings of conference Full-text Database 1 Hits
1 YAN Xi,XIONG Chunyan,ZHANG Yun,WANG Yuanyuan,SUN Yupeng,MA Ruiping,(College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,Hebei,China);Research progress of catalyst in selective hydrogenation of benzene to cyclohexene[A];[C];2012
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Zhang Li,Liu Rongxun,Zhang Xiaoyen and Ren Xuehua(Department of Chemical Engineering);Study on the Reaction Kinetics of Hydroqenation for Furfural over a Copper-base Catalyst[J];;1987-01
2 CAO Mao-sheng,LIU Hai-tao, LI Chen-sha,CHEN Yu-jin, MA Wen-you;An Approch to Surface Treating for Carbon Nanotubes[J];China Surface Engineering;2002-04
3 Zhang Xi-ping, Liu Ding-Jiang and Deng Jing-fa (Department of Chemistry, Fudan University, Shanghai, 200433);STUDIES ON AMORPHOUS Co-P/SiO_2 CATALYST[J];Chinese Journal of Catalysis;1990-03
4 Li, Tong-xin; Li, Hui-min; Cui, Shen; Li, Meng and Li, Shi-jing(Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023);CATALYTIC BEHAVIOR OF AMORPHOUS Ni-B ALLOY FOR BENZENE HYDROGENATION[J];Chinese Journal of Catalysis;1991-06
5 Zhang, Wen-zhong, Su, Gui-qin, Jiao, Feng-ying,Temure, and Yin, Yuan-qi (Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000);STUDY ON THE INTRINSIC PROPERTIES AND CATALYTIC ACTIVITIES OF RANEY NICKEL CATALYSTS[J];Chinese Journal of Catalysis;1992-01
6 Xu, Hui-zhen; Shi,Jie-hua;Wang, Li-shengand Lu,Li-xin(Department of Chemical Engineering, Zhejiang Institute of Technology, Hangzhou 310014);ADSORETiON-DESORPTION AND SURFACE HYDROGENATION OF CO ON SUPPORTED Ru CATALYSTS[J];Chinese Journal of Catalysis;1993-04
7 Wang Minghui, Li Hexing (Department of Chemistry, Shanghai Normal University, Shanghai 200234) Deng Jingfa (Department of Chemistry, Fudan University, Shanghai 200433);PREPARATION OF ULTRAFINE Co B AMORPHOUS ALLOY CATALYST AND ITS CATALYTIC PERFORMANCE IN HYDROGENATION OF ACETONITRILE[J];CHINESE JOURNAL OF CATALYSIS;1999-05
8 Ma Aizeng (Research Institute of Petroleum Processing, SINOPEC, Beijing 100083);CHARACTERIZATION AND CATALYTIC PERFORMANCE OF SUPPORTED AMORPHOUS Ni B ALLOY CATALYSTS[J];CHINESE JOURNAL OF CATALYSIS;1999-06
9 Chen Changrong 1, Bian Guozhu 1, Jiang Ming 1, Wan Xiaohong 2, Li Zhongrui 1, Wei Shiqiang 2,3 (1 Department of Chemical Physics; 2 National Synchrotron Radiation Laboratory; 3 Center for Fundamental Physics, University of Science and Technol;EFFECT OF CERIUM ADDITION UPON THE ACTIVITY AND THE THERMOSTABILITY OF ULTRAFINE AMORPHOUS Ni P ALLOY CATALYSTS FOR BENZENE HYDROGENATION[J];CHINESE JOURNAL OF CATALYSIS;1999-06
10 ZHANG Guosheng 1,2 , SHEN Ningfu 1 (1 Materials Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China; 2 Research Center for Materials, Zhengzhou University of Technology, Zhengzhou 450002, China);Catalytic Performance of Ni Zr Al Amorphous Alloy Catalyst for Hydrogenation of Benzene[J];CHINESE JOURNAL OF CATALYSIS;2000-01
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 ZHOU Gongbing, LIU Jianliang, XU Ke, PEI Yana, QIAO Minghuab, FAN Kangnian Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China;Liquid-Phase Partial Hydrogenation of Benzene over Ru/MgAl_2O_4 Catalyst: Effect of Calcination Temperature of MgAl_2O_4[J];Chinese Journal of Catalysis;2011-09
2 WANG Weiyan,YANG Yunquan*,LUO Hean,PENG Huizuo,ZHANG Xiaozhe,HU Tao School of Chemical Engineering,Xiangtan University,Xiangtan 411105,Hunan,China;Preparation and Hydrodeoxygenation Properties of Ni-Co-W-B Amorphous Catalyst[J];Chinese Journal of Catalysis;2011-10
3 QIN Yanfei, XUE Wei, LI Fang, WANG Yanji, WEI Junfang Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China;Preparation of Ru-[bmim]BF_4 and Its Catalytic Performance for Selective Hydrogenation of Benzene[J];Chinese Journal of Catalysis;2011-11
4 QI Xue, SHI Qiujie, CHEN Weiqing, ZHANG Rongbin* Institute of Applied Chemistry, Nanchang University, Nanchang 330031, Jiangxi, China;Effect of Mo on Performance of Ni-B/Boehmite Amorphous Alloy Catalyst for Thiophene Hydrodesulfurization[J];Chinese Journal of Catalysis;2012-03
5 SUN Haijie,PAN Yajie,WANG Hongxia,DONG Yingying,LIU Zhongyi *,LIU Shouchang Department of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;Selective Hydrogenation of Benzene to Cyclohexene over a Ru-Zn Catalyst with Diethanolamine as an Additive[J];Chinese Journal of Catalysis;2012-04
6 SONG Hua~* , Yu Hongkun, LIU Quanfu, II Feng(College of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,Heilongjiang,China);Advances in modification of Ni-B and Ni-P amorphous ahoy catalysts[J];Industrial Catalysis;2009-03
7 LI Jian-xiu(Pingdingshan Institute of Industry Technology,Henan Pingdingshan 467000,China);Research on Process Lines in the Production of Chloroxyclohexene[J];Guangzhou Chemical Industry;2011-14
8 XIE Yaling, XIAO Nan, LING Zheng, LIU Yue, YU Chang, QIU Jieshan Carbon Research Laboratory, Liaoning Key Lab for Energy Materials and Chemical Engineering, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China;Flower-Like Co-Ni/C Bimetallic Catalysts for the Selective Hydrogenation of o-Chloronitrobenzene[J];Chinese Journal of Catalysis;2012-12
9 LOU Shujie,XIAO Chaoxian,SUN Geng,KOU Yuan* College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China;A new method for preparation of cylohexanol from benzene[J];Chinese Journal of Catalysis;2013-01
10 SUN Haijie, JIANG Houbing, LI Shuaihui, WANG Hongxia, PAN Yajie, DONG Yingying, LIU Shouchang, LIU Zhongyi * College of Chemistry and Molecular Engnineering, Zhengzhou University, Zhengzhou 450001, Henan, China;Selective hydrogenation of benzene to cyclohexene over nanocomposite Ru-Mn/ZrO_2 catalysts[J];Chinese Journal of Catalysis;2013-04
China Proceedings of conference Full-text Database 2 Hits
1 XUE Wei WANG Dong-dong WANG Yan-ji LIU Yuan WEI Jun-fang (Key Laboratory of Green Chemical Technology & High-Efficient Energy Saving of Hebei Province,Hebei University of Technology,Tianjin 300130,China);THE ONE-POT SYNTHESIS OF CYCLOHEXANOL FROM BENZENE[A];[C];2008
2 Sun Haijie;Chen Lingxia;Li Yongyu;Zhao Wenbo;Wang Xin;Institute of Environmental and Catalytic Engineering,Department of Chemistry,Zhengzhou Normal University;;Effect of Zn precusors on the performance of Ru-Zn catalysts for benzene selective hydrogenation to cyclohexene[A];[C];2014
【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 Ma Aizeng (Research Institute of Petroleum Processing, SINOPEC, Beijing 100083);CHARACTERIZATION AND CATALYTIC PERFORMANCE OF SUPPORTED AMORPHOUS Ni B ALLOY CATALYSTS[J];CHINESE JOURNAL OF CATALYSIS;1999-06
2 Chen Changrong 1, Bian Guozhu 1, Jiang Ming 1, Wan Xiaohong 2, Li Zhongrui 1, Wei Shiqiang 2,3 (1 Department of Chemical Physics; 2 National Synchrotron Radiation Laboratory; 3 Center for Fundamental Physics, University of Science and Technol;EFFECT OF CERIUM ADDITION UPON THE ACTIVITY AND THE THERMOSTABILITY OF ULTRAFINE AMORPHOUS Ni P ALLOY CATALYSTS FOR BENZENE HYDROGENATION[J];CHINESE JOURNAL OF CATALYSIS;1999-06
3 Ye Daiqi, Pang Xianshen, Huang Zhongtao Department of Chemical Engineering South-China University of Technology Guangzhou 510641;New Technology for the Production of Polyamide—The Selective Hydrogenation of Benzene to Cyclohexene[J];Chinese Polymer Bulletin;1993-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved