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《Chinese Journal of Catalysis》 2010-08
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The Development of Cobalt-Based Catalysts for Fischer-Tropsch Synthesis

SUN Yuhan1,2,*,CHEN Jiangang1,*,WANG Jungang1,JIA Litao1,HOU Bo1,LI Debao1,ZHANG Juan1 1Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,Shanxi,China 2Shanghai Advanced Research Institute,Shanghai 201203,China  
Fischer-Tropsch (F-T) synthesis is an important route to utilize fossil resources such as coal and natural gas.The key point is the control of catalyst selectivity,that is how to suppress methane formation and to improve distillate selectivity.In the past decade,Co-based F-T synthesis catalysts and related scale-up were investigated in our laboratory,including the relationship between cobalt dispersion,reducibility,and methane formation along with the hydrophobic modification and the core-shell structure.It was found that CH4 selectivity is correlated with the reducibility of cobalt,which depends on its particle size.Based on these,Co-based catalysts have been developed for the scale-up with the feature of low CH4 and high heavy hydrocarbon selectivity.Catalyst I is now subjected to the demo-plant of over 5 000 t/a,and Catalyst II (with much low CH4 selectivity) has operated for more than 8 000 h.
【Fund】: 国家重点基础研究发展计划(973计划 2005CB221402);; 煤转化国家重点实验室自主基金项目(08BWLD16A1)
【CateGory Index】: TQ529.2
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【Citations】
Chinese Journal Full-text Database 1 Hits
1 CHENG Meng~(1,2),FANG Ke-gong~1,CHEN Jian-gang~1,SUN Yu-han~1(1.State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China;2.Graduate School of the Chinese Academic of Sciences,Beijing 10039,China);Characterization and catalytic behavior of Co/Ru/SiO_2 catalysts prepared from hydrophilic and hydrophobic supports[J];Journal of Fuel Chemistry and Technology;2006-03
【Co-citations】
Chinese Journal Full-text Database 3 Hits
1 Xu Zhen'gang Luo Wei Wang Naiji and Xiao Cuiwei(Beijing Research Insititute of Coal Chemistry,China Coal Research Institute,100013 Bejing);RESEARCH PROGRESS OF CARRIERS FOR FISCHER-TROPSCH SYNTHESIS CATALYSTS[J];Coal Conversion;2008-03
2 Li Yuping1,2,3, Wang Tiejun1,2, Wu Chuangzhi1,2, Lü Yongxing1,2,3, Li Haibin1,2(1. Key Laboratory of Renewable Energy and Natural Gas Hydrate, Chinese Academy of Science, Guangzhou Guangdong 510640, China; 2. Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou Guangdong 510640, China; 3. Graduate School of Chinese Academy of Science, Beijing 100049, China);Effect of Co/SiO_2 Catalyst Modified by Zeolites on Fischer-Tropsch Synthesis of Gasoline-Cut Hydrocarbons[J];Petrochemical Technology;2008-05
3 LI Yu-ping1,2,3,WANG Tie-jun1,2,WU Chuang-zhi1,2,LI Xin-jun1,2,LU Yong-xing1,2,3 (1.Key Laboratory of Renewable Energy and Gas Hydrate,Chinese Academy of Sciences,Guangzhou 510640,China;2.Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences,Guangzhou 510640,China;3.Graduate School,Chinese Academy of Science,Beijing 100039,China);Influence of SiO_2/HZSM-5 supports on gasoline-range hydrocarbons synthesis with cobalt-based catalysts[J];Modern Chemical Industry;2008-02
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 ZHU Tuo-quan 1,2, FANG Ke-gong1, ZHANG Jun-ling1, ZHAO Hong-xia1, CHEN Jian-gang1, SUN Yu-han1 (State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China; 2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China);Study on reaction performance of Co/ZrO_2-Al_2O_3 catalysts for Fischer-Tropsch synthesis[J];Journal of Fuel Chemistry and Technology;2005-03
2 ZHU Zhe-quan~1, 2, FANG Ke-gong~1, CHEN Jian-gang~1, SUN Yu-han~1(1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry,Chinese Academy of Sciences, Taiyuan 030001,China;2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China);Effect of pH value of impregnating solution on the performance of Co/TiO_2 catalyst for Fischer-Tropsch synthesis[J];Journal of Fuel Chemistry and Technology;2005-04
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