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《Chinese Journal of Catalysis》 2010-09
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Synthesis of Nickel Phosphate Nanotubes and Their Catalytic Performance for Cyclohexene Epoxidation

WU Guang1,2,WANG Anjie1,*,LI Xiang1,WANG Yao1,HU Yongkang1 1State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012,Liaoning,China 2School of Chemistry and Material Sciences,Heilongjiang University,Harbin 150080,Heilongjing,China  
Nickel phosphate nanotubes(NiPO-NTs) with a uniform pore size distribution were prepared by urea-assisted hydrothermal synthesis in the absence of any organic template.Calculations from N2 adsorption-desorption isotherms of NiPO-NTs revealed a narrow pore distribution around 2.7-4.2 nm and a surface area of 96.6 m2/g.NiPO-NTs was used to catalyze the epoxidation of cyclohexene using hydrogen peroxide as the oxidant.Infrared spectroscopy of adsorbed pyridine and NH3 temperature-programmed desorption characterization results showed that the weak Lewis acid was predominant on the surface of NiPO-NTs.CH3CN was found to be a suitable solvent for the epoxidation.The reaction conversion increased with increasing reaction temperature and H2O2/cyclohexene molar ratio,whereas the selectivity for epoxycyclohexane increased with decreasing temperature and increasing H2O2/cyclohexene molar ratio.High cyclohexene conversion(50.6%) and selectivity for epoxycyclohexane(72.1%) were obtained at 60 oC,6 h,and H2O2/cyclohexene of 3.
【Fund】: 国家高科技研究发展计划(863计划 2008AA030800);; 国家自然科学基金(20333030 20503003 20773020)
【CateGory Index】: O643.32
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【Citations】
Chinese Journal Full-text Database 3 Hits
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 XIAO Yi1,2,HUANG Hong-mei1,YIN Du-lin1,2*,YUE Li-yan2,MAO Li-qiu2,WANG Ji-hui3 (1.Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research,Ministry of Education;2.Institute of Fine Catalysis and Synthesis;3.Key Laboratory of Resource Fine-Processing and Advanced Materials of Hunan Province,Hunan Normal University,Changsha 410081,China);Oxidation of p-Propenylanisole with Hydrogen Peroxide over Oxovanadium Aromatic Carboxylates Mediated by Organic Bases[J];Journal of Molecular Catalysis;2011-03
2 DU Ji-min,LI Qiang,FU Lei-xia,LIU Hui-qiao,LI Kai-ge(Chemistry and Chemical Industry School,Anyang Normal University,Anyang He′nan 455002,China);V_2O_5/SiO_2 catalyst: synthesis,characterization and investigation of their catalytical property[J];Journal of Hebei University of Science and Technology;2010-02
3 LI Jiaqi1,2,YIN Dulin2,XU Qiong2,GUO Jun1,ZHOU Hui1,CHEN Meng1(1 Department of Chemistry and Material Science,Hunan Institute of Humanities,Science and Technology,Loudi 417000,Hunan,China;2 Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research,Ministry of Education,Institute of Fine Catalysis and Synthesis,Hunan Normal University,Changsha 410081,Hunan,China);Oxidation of styrene to benzaldehyde catalyzed by Dawson-type tungstophosphate[J];Chemical Industry and Engineering Progress;2008-07
4 LI Jia-qi,GUO Jun(Department of Chemistry and Material Science,Hunan Institute of Humanities,Science and Technology,Loudi 417000,China);Oxidation of styrene catalyzed by quaternary ammonium molybdovanadophosphates with H_2O_2[J];Chemical Reagents;2008-06
5 LI Jia-qi1,2,GUO Dan1,YIN Du-lin1,XIAO Yi1,MAO Li-qiu1(1.Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research,Ministry of Education,Institute of Fine Catalysis and Synthesis,Hunan Normal University,Changsha 410081,China;2.Department of Chemistry and Material Science,Hunan Institute of Humanities,Science and Technology,Loudi 417000,China);Study on Oxidation of β-Pinene with Hydrogen Peroxide Catalyzed by Benzoic Acid Oxovanadium[J];Chemistry and Industry of Forest Products;2008-02
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7 WEI Jun-fang,WANG Yan-ji,LI Juan,XUE Wei(Key Laboratory of Green Chemical Technology and High-efficient Energy Saving of Hebei Province,Hebei University of Technology,Tianjin 300130,China);Monodisperse submicroscopic HZSM-5 zeolite:preparation and application in cyclohexene hydration[J];Journal of Hebei University of Technology;2011-04
8 XIAO Yi1,2,HUANG Hongmei1,YIN Dulin1,2,MAO Liqiu2,WANG Jihui3(1Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research,Ministry of Education; 2Institute of Fine Catalysis and Synthesis;3 Key Laboratory of Resource Fine-Processing and Advanced Materials of Hunan Province,Hunan Normal University,Changsha 410081,Hunan,China);Oxidation of isoeugenol to vanillin with hydrogen peroxide catalyzed by modified-V_2O_5[J];Chemical Industry and Engineering Progress;2011-10
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【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
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10 MA Xiping1, HU Yanshao2, GU Shumin1 , WU Jianwei2(1.Shenma Nylon 66 Salt Co.Ltd,Pingdingshan 467000,China;2.Technology Center of China Shenma Group Co.Ltd, Pingdingshan 467000,China);STUDY AND OPTIMUM OF PROCESS PARAMETERS FOR CYCLOHEXENE HYDRATION[J];Science & Technology In Chemical Industry;2003-04
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