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《Chinese Journal of Catalysis》 2012-12
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Montmorillonite-Supported Copper(Ⅰ)for Catalyzing N-Arylation of Nitrogen Heterocycles

QI Xiaolong1,ZHOU Limei1,a,JIANG Xiaohui1,b,FAN Hongwei1,FU Haiyan2,CHEN Hua2 1Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province,China West Normal University,Nanchong 637002,Sichuan,China 2 Institute of Homogeneous Catalysis,College of Chemistry,Sichuan University,Chengdu 610064,Sichuan,China  
Montmorillonite-supported copper (Ⅰ) catalyst has been prepared by a simple ion exchange method.The resulting catalyst was characterized by X-ray diffraction,X-ray photoelectron spectroscopy,scanning electron microscopy,and energy dispersive X-ray spectrometry,with results showing that Cu+ had been successfully intercalated into the interlayer of Montmorillonite.The catalyst showed high levels of activity towards the N-arylation of nitrogen heterocycles with aryl chlorides or bromides.Furthermore,the catalyst could be reused up to four times without any significant loss in activity.
【Fund】: supported by the Open Project of Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province(CSPC2010-3);; the Educational Department of Sichuan Province (11ZA035);; the Doctoral Initiating Project of China West Normal University (10B007)~~
【CateGory Index】: O643.32
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【References】
Chinese Journal Full-text Database 1 Hits
1 Ming Jin, Dan Zhao, Guozhen He, Yao Tong, Shiqing Han * College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 211816, Jiangsu, China;Substrate-promoted copper-catalyzed N-arylation of amino alcohols with aryl iodides in water[J];Chinese Journal of Catalysis;2013-09
【Co-references】
Chinese Journal Full-text Database 1 Hits
1 Zhang,Jingxian Yin,Huiqing Han,Shiqing(College of Biotechnology and Pharmaceutical Engineering,Nanjing University of Technology,Nanjing 211816);Copper-Catalyzed N-Arylations of Nitrogen-Containing Heterocycles in Water[J];Chinese Journal of Organic Chemistry;2012-08
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