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《Chinese Journal of Catalysis》 2015-07
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Br?nsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols

Tao Chang;Leqin He;Xiaojing Zhang;Mingxia Yuan;Shenjun Qin;Jiquan Zhao;Key Laboratory for Resource Exploration Research of Hebei Province,Hebei University of Engineering;School of Chemical Engineering,Hebei University of Technology;  
Quaternary ammonium Br?nsted acid surfactant-combined dicationic ionic liquids(BASDILs) based on zwitterionic 1,2-bis[N-methyl-N-(3-sulfopropyl)-alkylammonium]ethane betaines and various anions were prepared and characterized. BASDILs possess properties similar to those of phase-separated catalysts and were applied to the catalytic synthesis of biodiesel from free fatty acids and alcohols. Several factors were investigated and the results indicated that [C12Sb][p-CH3C6H4SO3] was the optimal catalyst, with good catalytic performance and reusability under mild conditions.
【Fund】: supported by the Science Foundation of Hebei Province(B2012402001 D2014402046);; Program for One Hundred Innovative Talents in Universities of Hebei Province(BR2-204);; and the Science and Technology Foundation of Universities of Hebei Province(Q2012030)~~
【CateGory Index】: TE667;O621.251
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