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《CHINESE JOURNAL OF CATAL YSIS》 1995-02
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STUDY ON THE CORRELATION BETWEEN SURFACE ACIDITY OF HZSM-5 ZEOLITES AND CATALYTIC ACTIVITY FOR n-BUTYL ACETATE SYNTHESIS IN LIQUID PHASE

Ma, De-fu ; Gu, Shu-zhen and Yang, Rong-bin (Department of Chemical Engineering, Shanghai University of Engineering Science, Shanghai 200051 )  
he surface acidity of HZSM-5 zeolites is determined by Hammett indicator method, and is correlated with the catalytic activity for synthesis of n--butyl acetate in liquid phase. It is found that the acid sitessuch as - 5. 6H0≤- 3. 0 and --3. 0H0≤+3. 3 make a greater contribution to the catalytic esterification with contribution ratios of 48.3% and 33. 0% respectively. When the surface acid content is converted toavailable acid content according to its contribution ratio to catalytic reaction, the correlation between available acid content and reaction velocityconstant is in correspondence with the rule of homogeneous acid catalytic reaction. For the n--butyl acetate synthesis reaction in liquid phasewith HZSM--5 (St/A1= 60) as catalyst: k= 7. 17[C]4.25.
【CateGory Index】: O623.624.1
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【References】
Chinese Journal Full-text Database 10 Hits
1 LI Shu-qin (Xiangfan University,Xiangfan 441053 China);Synthesis of Isoamyl Propionate Over Molecular Sieve Catalyst[J];辽宁化工;2009-12
2 HOU Qi-jun (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China);Greening of Surfactant Industry[J];精细与专用化学品;2008-19
3 DING Li,TANG Zhi-gang,DUAN Zhan-ting (Chemical Engineering Department,Tsinghua University,Beijing 100084,China);A Switch Method of Synthesis Process for Ethyl Acetate or Propyl Acetate by Reactive Distillation[J];精细化工;2006-09
4 JIA Li-hua,LI Hua,WU Li-yan,GUO Xiang-feng(College of Chemical and Chemistry Engineering,Qiqihaer University,Qiqihaer 161006,China);Synthesis of n-butyl acetate over acid-treated cross-linked montmorillonite[J];工业催化;2006-01
5 TONG Zhang fa,LUO Cheng gang, LI Zhong min, LIAO Dan kui (College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004,China);Preparation of hydroxyl zirconium cross-linked bentonite and its catalytic performance in esterification[J];广西大学学报(自然科学版);2002-01
6 Ma Defu Li Yuan (Dean's office,Shanghai University of Engineering Science,Shanghai 200336);STUDY ON SYNTHESIS OF n-BUTYL ACETATE WITHWO_3-TiO_2-SO_4~(2-) SOLID SUPERACID AS CATALYST[J];上海工程技术大学学报;2000-03
7 Cao Zhengtai ;Liu Shizhong ;Dong Junping ;Chen Jinyang(Faculty of Chemistry and Material Science, Hubei University, Wuhan 430062, China);Study on the Sunthesis of Butyl Acetate Using Supperted Heteropoly Blue as Catalyst[J];湖北大学学报(自然科学版);1999-01
8 Li Bin Li Jingling Liang Yuning ( College of Chemistry and Chemical Engineering,Guangxi Univ.,Nanning,530004 );Characteristics and Activity of Catalytic Esterification in Liquid Phase of Mo/HZSM5 Zeolites[J];广西大学学报(自然科学版);1999-01
9 Lin Shen Yu Yaqin Li Xiaojing Chen Shouzheng (Department of Chemistry,Fujian Teachers University,Fuzhou 350007);Study on Surface Acidity of Bentonite Supported Tungstophosphorous Heteropoly Acid Catalyst and Catalytic Activity for Esterification[J];福建师范大学学报(自然科学版);1998-04
10 Xiao Zijing;Huang Jitai;Dai Jingcao(Inst. of Mater. Phys. Chem., Huaqiao Univ., 362011,Quanzhou);Measuring Surface Acidity of Modified Clay by Adopting Adsorption Isotherm[J];华侨大学学报(自然科学版);1997-02
【Citations】
Chinese Journal Full-text Database 2 Hits
1 Li Xuanwen She Liqin Liu Xingyun(Department of Chemistry, Peking University);STUDY ON THE CORRELATION BETWEEN CATALYTIC ACTIVITY AND SURFACE ACIDITY OF LaHY ZEOLITES[J];燃料化学学报;1990-03
2 Ma Defu Gu Shuzhen (Department of Chemical Engineering,Shanghai University of Engineering Science);Study on Synthesis of n-Butyl Acetate in Liquid Phase with Zeolites as Catalysts[J];石油化工;1989-07
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZENG Yong-jun,YU Hai-jiang,SHI Li(Research Institute of Petroleum Processing,East China University of Science and Technology,Shanghai 200237,China);Surface Acidity and Catalytic Activity of Y-zeolite Catalysts[J];华东理工大学学报(自然科学版);2008-05
2 LI Zijin,HUANG Baohua,ZHANG Weigang,ZHANG Kun,FANG Yanxiong,ZHOU Beilei (Faculty of Chemical Engineering & Light Industry,Guangdong University of Technology,Guangzhou 510006,Guangdong,China);Kinetic studies on synthesis of n-butyl acetate catalyzed by ionic liquid [Hnmp]HSO_4[J];工业催化;2008-03
3 ZENG Yong-jun,WANG Yi-nan,WANG Xin,SHI Li(Petroleum Processing Research Center,East China University of Science and Technolgy,Shanghai 200237,China);Surface Acidity and Catalytic Activity of Nb(OH)_5-modified Zeolite[J];化学世界;2007-11
4 Chen Guo-liang(Qiqihar University,161006);Synthesis of fatty alcohol chloroacetates[J];齐齐哈尔大学学报;2007-03
5 HUANG Qi-wei (Department of Bioengineering and Environmental Science,Changsha University,Changsha 410003,China);H-βZeolite-Catalysed Esterification Reactions of Acetic Acid[J];湖南师范大学自然科学学报;2006-01
6 ZHAO Zhen-hua (Department of Applied Chemistry and Environmental Science,Changsha University,Changsha 410003,China);Catalytic Synthesis of Amyl Pentanoate by Aluminophosphate Molecular Sieve[J];合成化学;2006-01
7 HUANG Qi-wei, ZHANG Shi-ying(Department of Applied Chemistry and Environmental Science, Changsha University, Changsha 410003, China);Studies on Esterification Reactions of Carboxylic Acids over Silicoaluminophosphate Molecular Sieve Catalysts[J];分子催化;2003-06
8 ZHAO Rui-lan, ZHAO Zhen-hua, LI Long (College of Chemistry and Chemical Technology, Hunan Normal University, Changsha 410081, China);Synthesis of Amyl Butyrate in Liquid-Solid Phase Using β Zeolites as Catalysts[J];合成化学;2003-06
9 LIU Han-wen, TAN Feng-jiao, YI Gui-yuan (Department of Chemistry, Xiangtan Normal University, Xiangtan 411201, China);Study on Catalytic Synthesis of n-Butyl Acetate by Dealuminated USY Zeolite[J];合成化学;2002-06
10 ZHAO Ruilan, ZHAO Zhenhua, HOU Yan(Department of Chemistry,College of Chemistry and Chemical Technology, Hunan Normal University,Changsh 410081,China);Studies on the Synthesis of Amyl Propionate Using β Zeolites as Catalysts[J];湖南师范大学自然科学学报;2002-04
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Qing1,SHAO Jun1,LIU Wei1,SANG Rong-li2(1.East Campus of Tangshan College,Tangshan 063002,China;2.Analysis and Testing Center,Hebei Polytechnic University,Tangshan 063009,China);Synthesis of isoamyl propionate catalyzed by activated carbon supported tungstosilicic acid under microwave irradiation[J];化学研究与应用;2008-09
2 LIAN Ping1,2,LI Lei1,Xue Jun1,QI Qi1,LAI Wen-ling1,LI Yong-xiu2(1.College of Chemistry and Life Science,Gannan Teachers' College,Ganzhou 341000,China; 2.Department of Chemistry,Nanchang University,Nanchang 330047,China);Catalytic Synthesis of Sucrose Palmitic Acid Ester by Rare Earth Solid Super Acid under Microwave Irradiation[J];稀土;2008-02
3 CHEN Ping1,2 GAO Liangjun2 ZHAI Yuchun2(1.School of Petrochemical Technology, Liaoning University of Petroleum & Chemical Technology, Fushun 113001, China;2.School of Petrochemical Technology, Zhejiang Ocean University, Zhoushan 31600, China; 3. Material and Metallurgy College,Northeastern University,Shenyang 110006, China);Application Advance of Microporous Molecular Sieve in Synthesis of Aromatic Ketone[J];香料香精化妆品;2008-01
4 JIANG Lin-lang,LIU Tian-hua,TONG Hui-juan,ZHENG Zhen-tao,Li Gong (Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China);Static Synthesis of Zeolites MCM-56 and its Catalytic Performance in Alkylation of Benzene with Long-chain Alkenes[J];江苏工业学院学报;2007-03
5 YU Shan-xin1,LIU Mei-yan1,WEN Rui-ming2(1.College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha Hunan 410081;2.Department of Chemistry and Environmentally Engineering,Hunan City University,Yiyang Hunan 413049);Synthesis of Isoamyl Propionate Catalyzed by Solid Acid[J];湖南文理学院学报(自然科学版);2007-03
6 Li Gong Liu Tianhua Jiang Linlang Tong Huijuan (Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,Jiangsu,China);MODIFICATION OF MCM-22 ZEOLITES AND ITS CATALYTIC PERFORMANCE IN ALKYLATION OF BENZENE WITH LONG-CHAIN ALKENES[J];精细石油化工;2007-04
7 WEN Qinwu,SHEN Jian,YANG Lina,LIU Chuanbin (Department of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning China);Synthesis of dodecylbenzene over supported HF/USY catalyst[J];工业催化;2007-07
8 Chen Guo-liang(Qiqihar University,161006);Synthesis of fatty alcohol chloroacetates[J];齐齐哈尔大学学报;2007-03
9 ZHOU Zhi-wei, WU Wen-liang, YU Li-pin, WANG Jun (College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China);Studies on Alkylation of Toluene with Tert-butyl Alcohol over USY Zeolite[J];高校化学工程学报;2006-06
10 SHAO Li-jun~1 SHEN Xi-hai~1 DONG Dan-hong~2 ZHANG Wei-guo~1 LIU Hong-mei~1 1 Dept of Chemistry,HNUST,Qinhuangdao Hebei,066600 2 Xingtai Medical College;China;Synthesis of Iso-amyl Propionate Catalyzed by P-Toluene Sulfonic Acid under Microwave Irradiation[J];河北科技师范学院学报;2006-04
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LIU Si-han;BAI Li-mei;WU Ying-ga;WANG Bin;LIU Zong-rui;Chemistry and Chemical Engineering collge, Inner Mongolia University for the Nationalities;;Progress in Performance Research and Preparation Method of Supported Heteropoly Acid Catalyst[J];生物化工;2015-01
2 ZUO Wei-yuan;TONG Hai-juan;Department of Chemistry and Life Sciences,Baise University;;The Synthesis of Butyl Acetate by Sodium Bisulfate Supported on Activated Carbon[J];广州化工;2014-18
3 Zhang Heng;Jinxi Research Institute of Chemical Industry Company Ltd.;;Research Progress in Catalytic Organic Reactions with Activated Clay[J];石化技术;2014-03
4 PAN Zhi-shuang;ZHANG Chen-xi;ZHOU Wei-jun;ZHANG Ai-ping;TAN Zheng-guo;Lanzhou Petrochemical Research Center,PetroChina;;Advances in studies of acidity of cross- linked clay[J];石化技术与应用;2014-04
5 ZHANG Ye-long;LI Yuan-yuan;JIA Chen;HAN Yu-wang;HU Yi;College of Science,Nanjing University of Technology;College of Chemistry and Chemical Engineering,Nanjing University of Technology;State Key Laboratory of Materials-Oriented Chemical Engineering,Nanjing University of Technology;;Research on stop-effect on the catalytic dehydration of ethanol over HZSM-5[J];燃料化学学报;2013-12
6 WANG Xueli;WANG Tinghai;HAN Yan;LI Yao;PetroChina Lanzhou Chemical Research Center;;Preparation of Al-rectorite[J];工业催化;2013-10
7 FU Rui(SGS-CSTC Standards Technical Services Tian Branch,Tianjin 300457,China);Development and Application of Bentonite Products with High Additional Values[J];河北化工;2013-04
8 HUANG Yan-qin(Department of Chemistry and Chemical Engineering,Xinxiang University,Xinxiang 453003,China);Preparation of Biodiesel by the Catalyst of Phosphotungstic Acid Supported by Bentonite[J];新乡学院学报(自然科学版);2013-02
9 Hao Xiangying1,2,Wei Jingfang2,Zhaorigetu2,Guo Haifu1(1.School of Chemistry and Chemical Engineering,Zhaoqing University,Zhaoqing 526061,China; 2.Inner Mongolia Normal University);Study on preparation and catalytic performance of SO_4~(2-)/Hangjin 2~# clay catalyst[J];无机盐工业;2012-12
10 Tan Hui,Gao Manglai,Luo Zhongxin,Gu Zheng,Shu Shenbao(State Key Laboratory of Heavy Oil Processing,College of Science,China University of Petroleum,Beijing 102249,China);Catalytic Activity of Al~(3+) Modified Bentonite for Benzylation of Toluene[J];石油化工;2012-11
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 She Liqin, Liu Xingyun and Li Xuanwen(Department of Chemistry, Beijing University);A STUDY OF THE CATALYTIC ACTIVITY,HYDRO-THERMAL STABILITY AND THE NATURE OF ACTIVE SITES OF LANTHANUM HYDROGEN Y ZEOLITES[J];催化学报;1980-04
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