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《CHINESE JOURNAL OF CATAL YSIS》 1996-03
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CHARACTERIZATION OF Cu BASED ZrO 2 SUPPORTED CATALYSTS FOR METHANOL SYNTHESIS

Liu Yuan 1, Hu Tiandou 2, Zhong Bing 1, Peng Shaoyi 1, Xie Yaning 2 (1 Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001; 2 Synchrotron Radiation Laboratory, Institute of High Energy Physics, Chinese Academy of Scie  
The structure of CuO/ZrO 2 catalysts and their reduced states has been characterized by means of XRD, EXAFS and ESR. It is found that CuO is the only compound containing copper in CuO/ZrO 2 and the ZrO 2 support has influence on the structure of CuO. CuO in CuO/ZrO 2 can disperse spontaneously at a proper calcination temperature. In the reduced catalyst samples, only metal copper is detected when the weight percent of CuO in CuO/ZrO 2 exceeds 12%; when the CuO content is 3 5%, metal copper is predominant but not exclusive, copper oxide also exists, in which the bond distance of Cu-O is between that of pure CuO and pure Cu 2O. With the decrease of the content of CuO in CuO/ZrO 2, the dispersion of CuO (for the CuO/ZrO 2) and metal copper (for the reduced samples) on ZrO 2 increases and the productivity of methanol from CO/2H 2 on per gram copper also increases.
【CateGory Index】: O643.36
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【References】
Chinese Journal Full-text Database 9 Hits
1 Kun Zhao;Fang He;Zhen Huang;Anqing Zheng;Haibin Li;Zengli Zhao;Key Laboratory of Renewable Energy,Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences;University of Chinese Academy of Sciences;;La_(1-x)Sr_xFeO_3 perovskites as oxygen carriers for the partial oxidation of methane to syngas[J];催化学报;2014-07
2 Jin Hongjian~1,Guo Jianmin~1 and Zong Qiuyun~2 (1.Tianji Coal Chemical Co.,Ltd.,Lucheng Shanxi 047507,China; 2.Qingdao University of Science and Technology,Qingdao Shandong 266042,China);Study on the Performance of the Zr-Ce-Promoted QDB-04 Catalyst and Its Application[J];煤化工;2011-01
3 GAO Zhihua,HUANG Wei,YIN Lihua,XIE Kechang Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology,Taiyuan 030024,Shanxi,China;Effect of La and Mn Promoters on Structure and Performance of CuZr Catalyst Prepared by Complete Liquid-Phase Technology[J];催化学报;2011-02
4 Zong Qiuyun1,Liu Bonan2,Zhou Chunli1 and Chen Nannan1(1.Qingdao Lianxin Chemical Co.,Ltd.,Jiaozhou 2611071;2.Jilin University,Changchun 133025);Performances and Application of Sulfur Tolerant QDB-04 Catalyst Promoted by Zr-Ce[J];煤化工;2008-02
5 Luo Tianyong, Li Chensha, Liang Tongxiang, Tang Chunhe (Institute of Nuclear Energy Technology, Tsinghua University, Beijing 102201);An Investigation of Zirconium Oxide Particles Supported on Carbon Nanotubes[J];稀有金属材料与工程;2004-08
6 Yang Peng-Cheng Cai Xiao-Hai Xie You-Chang(College of Chemistry and Molecular Engineering, Peking University,Beijing 100 871);Studies on the Dispersion Structure of Co-precipitated CuO-ZrO_2 Mixed Oxides[J];物理化学学报;2003-08
7 Hou Xianglin Gao Yinben Chen Songying (State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences Taiyuan);STUDY ON EFFECTS OF SUPPORTS ON CuO DESULFURIZATION PERFORMANCE AT HIGHTEMPERATURE[J];燃料化学学报;1998-05
8 Liu Yuan (Department of Chemical Engineering,Inner Mongolia Polytechnic University,010062,Huhhot,PRC);CHARACTERIZATION OF THE INTERACTION OF COPPER AND ZIRCONIA IN CuO/ZrO 2[J];内蒙古工业大学学报(自然科学版);1998-01
9 Liu Yuan, Hu Zeshan, Zhong Bing, Peng Shaoyi (Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001);TPR STUDY OF CuO/ZrO 2 CATALYSTS FOR METHANOL SYNTHESIS[J];催化学报;1996-03
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Liu, Yuan;Zhong, Bing; Wang, Qin and Peng, Shao-yi(Shanxi Institute of Coal Clemistry, Chinese Academy of Sciences,Taiyuan 030001);STUDY OF CuO/ZrO_2 CATALYSTS FOR METHANOL SYNTHESIS FROM CO/H_2[J];催化学报;1995-06
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 SUN Kai;TANG Yu;HAN Tao;ZHANG Qiang;BIAN Zhongkai;HUANG Wei;Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province,Taiyuan University of Technology;;Effect of different silica sources on catalytic performance of Cu-Zn-Si-Al catalyst for dimethyl ether synthesis in slurry reactor[J];天然气化工(C1化学与化工);2016-03
2 CHEN Yue-xian;WANG Yan;MA Jing-hong;LI Rui-feng;Institute of Special Chemicals,Taiyuan University of Technology;;Preparation of mesoporous CuO/γ-Al_2O_3 for one-step synthesis of dimethyl ether from syngas[J];燃料化学学报;2015-01
3 ZHANG Ming-Yu;WANG Hua;GAO Wen-Gui;Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction,Ministry of Education,Kunming Univesity of Science and Technology;State Key Laboratory Breeding Base of Complex Nonferrous Metal ResourcesCleaning Utilization inYunnan Province;;Preparation of CuO-ZnO-ZrO_2 catalysts for the hydrogenation of carbon dioxide to methanol[J];四川大学学报(自然科学版);2013-06
4 ZHANG Mingyu,WANG Hua,GAO Wengui(Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction,Ministry of Education,Kunming University of Science and Technology,Kunming 650093,Yunnan,China;State Key Laboratory Breeding Base of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province,Kunming 650093,Yunnan,China);Preparation of CuO-ZnO-ZrO_2 catalysts for methanol synthesis by vacuum freeze drying[J];化工进展;2013-06
5 LI Li-chao(Hejing Technique Co.,Ltd.,Jiaozuo Coal Group,Henan Jiaozuo 454191,China);Properties of ZrO_2 and the Application Development in the catalysis[J];广州化工;2013-10
6 CUI Xiao-Xi1 FAN Hui2 ZHENG Hua-Yan1 LI Zhong,1(1Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology,Taiyuan 030024,China)(2Sedin Engineering Company Limited,Technology Center,Taiyuan 030024,China);Influence of Solvent Polarity on Microstructure of Precursors and CuO/ZnO/Al_2O_3 Catalysts Aged under Microwave Irradiation[J];无机化学学报;2012-03
7 FAN Hui LI Zhong ZHENG Hua-Yan LIU Yan YAN Shao-Wei(Key Laboratory of Coal Science and Technology,Ministry of Education and Shanxi Province, Taiyuan University of Technology,Taiyuan 030024,China);Influence of Microwave Irradiation on Phasetransition in Preparation of Precursor of CuO/ZnO/Al_2O_3 Catalysts for Slurry Methanol Synthesis[J];无机化学学报;2011-03
8 GAO Zhihua,HUANG Wei,YIN Lihua,XIE Kechang Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology,Taiyuan 030024,Shanxi,China;Effect of La and Mn Promoters on Structure and Performance of CuZr Catalyst Prepared by Complete Liquid-Phase Technology[J];催化学报;2011-02
9 CHEN Gaoming1,WANG Hua2,GAO Wengui2,ZHANG Jian1,WEI Gang1(1 Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650224;2 Faculty of Metallurgy and Energy Engineering,Kunming University of Science and Technology,Kunming 650093);Direct Synthesis of DME by CO_2 Hydrogenation with CuO-CeO_2-ZrO_2/ HZSM-5 Catalysts[J];材料导报;2010-14
10 Yang Zhiqin,Yang Fei,Liu Rong (School of Power Engineering,Nanjing Normal University,Nanjing 210042,China);The Influence of Temperature on Zirconia Nanoparticles[J];南京师范大学学报(工程技术版);2010-01
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 MA Zhong-yi1,YANG Cheng2,ZHOU Wei1,ZHANG De-sheng1,LI Zheng1,WEI Wei2,SUN Yu-han2(1.Research Institute of Jilin Petrochemical Company,Ltd.,PetroChina,Jilin 132021,China;2.State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China);Effect of zirconia surface properties on the catalytic performance of Cu/ZrO_2 for CO hydrogenation[J];燃料化学学报;2009-02
2 DAI Xiaoping 1, 2, YU Changchun 1, LI Ranjia 1, WU Qiong 1, SHI Kaijiao 1, HAO Zhengping 2 (1. The Key Laboratory of Catalysis CNPC, University of Petroleum, Beijing 102249, China; 2. Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China);Effect of calcination temperature and reaction conditions on methane partial oxidation using lanthanum-based perovskite as oxygen donor[J];Journal of Rare Earths;2008-03
3 Guo Jianmin1,Ding Minggong1,Liu Jie2,Wang Luyuan2(1.Tianji Coal Chemical Industry Group Co.,Ltd.of Shanxi Province Luchen 047507;2.Shandong Lianxin Chemical Co.,Ltd.Jiaozhou 266317);Industrial Side-Line Experiment and Use of Type QDB-04 Sulfur-Tolerant Shift Catalyst[J];化肥工业;2007-03
4 Sun Yongkui,Hu Zhaofang,Dong Zhengqing(Guotai Chemical Industry Co.of Yankuang Group of Shandong Province Tengzhou 277527);Use of Type QDB-04 Sulfur-Tolerant CO Conversion Catalyst in Methanol Unit by Texaco Coal-Water Slurry Gasification Process[J];化肥工业;2007-03
5 Jiang Hongtao~(1,2) Li Huiquan~(1* *) Zhang Yi~(1)(1.The Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China;2.Graduate School of the Chinese Academy of Sciences,Beijing 100049,China);Tri-Reforming of Methane to Synthesis Gas[J];化学进展;2006-10
6 WU, Gui-Sheng WANG, Lu-Cun LIU, Yong-Mei CAO, Yong* DAI, Wei-Lin HE, He-Yong FAN, Kang-Nian* (Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials at Department of Chemistry, Fudan University, Shanghai 200433);Research on the Role of Reverse Hydrogen and Water Spillover in Methanol Decomposition over Cu/ZrO_2 Catalyst[J];化学学报;2006-10
7 GAO Zhihua, HUANG Wei*, HAO Lifeng, XIE Kechang (Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China);Liquid-Phase Preparation of CuO/ZrO_2 Catalyst Used in Slurry Reactors and Its Catalytic Activity for CO Hydrogenation[J];催化学报;2006-01
8 CHEN Yong-Hong* ,1,2 WEI Yi-Jun1 LIU Xing-Qin2 MENG Guang-Yao2 (1Center of Experiment and Communication, Huainan Normal University, Huainan, Anhui 232001) (2Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026);Characterization and Properties of La_(1-x)Sr_xFeO_(3-δ) with Perovskite-type Structure[J];无机化学学报;2006-01
9 ;DME A Solution for Energy Security and Environmental Protectionin China[J];中国能源;2005-11
10 Li Ranjia1 et al., Zhang Zhixiang2(1. Catalysis Key Laboratory of CNPC, University of Petroleum; 2. Daqing Petrochemical Company of Petrochina CO., LTD.).;PARTIAL OXIDATION OF NATURAL GAS TO SYNTHESIS GAS USING LATTICE OXYGEN FROM AFeO_3(A=La, Nd, Sm, Eu) PEROVSKITE[J];石油与天然气化工;2004-S1
【Secondary References】
Chinese Journal Full-text Database 9 Hits
1 WANG Xuetao;HU Haipeng;SU Xiaoxin;ZHANG Xiaolong;LAN Weijuan;LIU Chunmei;Department of Energy and Power Engineering, Henan University of Science and Technology;;Experimental study on selective catalytic reduction of NO at low temperature by active carbon fibers supported copper oxide and zirconium catalyst[J];热力发电;2017-10
2 Zhang Xiangling;Ma Qingxiang;Zhao Tiansheng;Geng Mengqian;Li Peng;State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering,College of Chemistry and Chemical Engineering,Ningxia University;;Progresses in the research for the catalytic hydrogenation of carbon dioxide to methanol[J];石油化工;2017-05
3 ZHAO Kun;SHEN Yang;HE Fang;HUANG Zhen;WEI Guoqiang;ZHENG Anqing;LI Haibin;ZHAO Zengli;Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences;Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences;University of Chinese Academy of Sciences;;Preparation of double perovskite-type oxide LaSrFeCoO_6 for chemical looping steam methane reforming to produce syngas and hydrogen[J];Journal of Rare Earths;2016-10
4 PENG Shu-jing;ZHOU Yan-jun;LIU Chong;Chemical & Environmental Engineering College, Liaoning University of Technology;;Simulation and Optimization of Methanol Reactor[J];辽宁工业大学学报(自然科学版);2016-03
5 ZHAO Kun;HE Fang;HUANG Zhen;WEI Guo-qiang;ZHENG An-qing;LI Hai-bin;ZHAO Zeng-li;Key Laboratory of Renewable Energy,Chinese Academy of Sciences;Guangdong Key Laboratory of New and Renewable Energy Research and Development;Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences;University of Chinese Academy of Sciences;;CaO/MgO modified perovskite type oxides for chemical- looping steam reforming of methane[J];燃料化学学报;2016-06
6 Zhai Kang;Li Kongzhai;Zhu Xing;Wei Yonggang;State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization,Kunming University of Science and Technology;Faculty of Chemical Engineering,Kunming University of Science and Technology;Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology;;Oxygen Exchange Materials Used in Two-Steps Thermochemical Water Splitting for Hydrogen Production[J];化学进展;2015-10
7 ZHANG Xiao-yang;ZHENG Xian-rong;HAN Peng;LIU Ze;CHANG Li-ping;State Key Laboratory Breeding Base of Coal Science and Technology Co-founded by Shanxi Province and the Ministry of Science and Technology,Taiyuan University of Technology;College of Electrical and Power Engineering,Taiyuan University of Technology;;Influence of carbon-based support on desulfurization performance of Zn-based sorbents prepared by high-pressure impregnation under ultrasound-assistance[J];燃料化学学报;2015-06
8 DONG Ping;WANG Zheng-de;Chemistry and Chemical Engineering School,Inner Mongolia University of Science and Technology;;The preparation of La_(0.67)Sr_(0.33)Mn_(0.7)Fe_(0.3) O_3 and the study of its photo catalytic performance[J];内蒙古科技大学学报;2015-01
9 ZHENG Xian-rong;CHANG Li-ping;BAO Wei-ren;FAN Bao-guo;REN Xiu-rong;College of Electrical and Power Engineering,Taiyuan University of Technology;State Key Laboratory Breeding Base of Coal Science and Technology Co-founded by Shanxi Province and the Ministry of Science and Technology,Taiyuan University of Technology;;Study on the performance of removing H_2S of Zn-Mn-Cu sorbents loaded on semi-coke from coal gas at mid-temperature[J];煤炭学报;2014-S2
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Liu Yuan; Zhong Bing; Peng Shaoyi; Wu Dong; Fan Wenhao (Institute of Coal Chemistry Academia Sinica, Taiyuan 030001);The Preparation and Characterization of Ultrafine ZrO_2[J];物理化学学报;1995-09
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