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《CHINESE JOURNAL OF CATALYSIS》 1997-05
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PERFORMANCE OF SUPPORTED NICKEL CATALYST FOR REFORMING OF CH 4 WITH CO 2 TO SYNGAS Ⅱ. Effect of Basic Promoters

Xu Zheng, Li Yumin, Zhang Jiyan, Chang Liu (Department of Chemical Engineering, Tianjin University, Tianjin 300072) He Fei [WT5”BX](State Key Laboratory of C 1 Chemical Engineering, Tianjin University, Tianjin 300072)  
The reaction activity for reforming of CH 4 with CO 2 to syngas and the resistance to carbon deposition of Ni/ γ Al 2O 3 catalyst with K 2O, Li 2O, MgO, La 2O 3 and CeO 2 as promoters were investigated using a fixed bed flow reactor as well as TG, XRD, XPS and TEM techniques, and the effect of impregnating order of promoter in preparation was also examined. All the catalyst samples with a promoter exhibit high resistance to carbon deposition, and except for K 2O and Li 2O, the other promoters are good for the reaction activity. The catalyst with MgO exhibits higher catalytic activity when MgO was added after Ni, but it is better to prevent coking if added before Ni. Among these samples, La 2O 3 promoted one has the best activity and resistance to carbon deposition, which can be attributed to maintaining the reduced Ni with lower valence, weakening the interaction of Ni with Al 2O 3 and promoting CO 2 conversion.
【CateGory Index】: O643.36
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