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《Acta Sedimentologica Sinica》 2008-03
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Kinetics of Gas from the Pyrolysis of Source Rock and Oil Cracking and Its Application in the Genesis of Natural Gases in Minfeng Area of Dongying Sag

WANG Xiu-hong1 JIN Qiang2 HU Xiao-qing3 CHEN Tao2 SONG Guo-qi4WANG Li2 WANG Juan2 LIN La-mei2 CHEN Zhi-wei5(1.Research Institute of Geosciences;Shengli Oilfield Company Ltd.,Sinopec,Dongying Shandong 257015;2.Department of Resources and Information,China University of Petroleum,Dongying Shandong 257061;3.Research Institute of Petroleum Exploration,CNOOC Research Center,Beijing 100027;4.Shengli Oilfield Company Ltd.SINOPEC,Dongying Shandong 257015;5.The Department for Gas Testing in Southwest Petroleum Engineering Administratire Centre;Shengli Oilfield Ltd.,Dazhou Sichuan 646154)  
It is controversial about the origin of the natural gas in Minfeng area.By using thermal simulation experiment of the sealed system, the genetic mechanism of Eocene source rocks and oils are discussed in the generation process of hydrocarbon,the generation kinetics of the gas and some individual hydrocarbon.The result shows that the activation value of oil cracking is 30 kJ/mol higher than the thermolysis of source rocks.At the mature phase,the cracking gas from source rock contains less aromatic hydrocarbons and cycloparaffinic hydrocarbons.In view of above,natural gases in Minfeng area is mainly from Eocene source rocks.
【Fund】: 国家自然科学基金项目(批准号:40572084、40272061)资助
【CateGory Index】: P618.13
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