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《Materials Protection》 2006-02
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Solid Inhibitor for Corrosion Prevention of Oil Well Pipe by High Temperature CO_2

YIN Cheng-xian 1,3 ,RUAN Lin-hua2,DING Wan-cheng2,LAN Xin-zhe1,FENG Yao-rong3,BAI Zhen-quan3(1.The Precious Metal Engineering Institute,Xi′an University of Arch. & Tech., Xi′an 710055,China;2.Exploitation Company of Heavy Oil,Xinjiang Oilfield Branch,Kelamayi 834000,China;3.The Key Laboratory for Mechanical and Environmental Behavior of Petroleum Tubes,China Natural Gas and Petroleum Group Corp.,Xi′an 710065,China)  
It needs a pump system for the introduction of conventional liquid corrosion-inhibitors used for oil well pipes and the relevant process has the disadvantages of inconvenient manipulation,continuous pumping,large dosage,short period of corrosion prevention,high cost,and fair corrosion protection efficiency.Thus maleic anhydride,sebacic acid,oleic acid,and dimeric dibasic acid were separately used to react with polyamine to generate quaternary ammonium of double-alkyl and double-annular imidazoline solid inhibitors.Static weight-loss method and dynamic simulation test method at high temperature and pressure were separately used to evaluate the inhibition efficiency of the resulting solid inhibitors and screen the desired raw materials.As the results,dimeric dibasic acid was suggested to be the favorite raw material for the synthesis of the solid inhibitor.It was feasible to introduce the solid inhibitor generated from dimeric dibasic acid at a concentration of 300 mg/L so as to decrease the corrosion rate of the oil well pipe subject to corrosion of saturated CO_2 at a temperature of 120 ℃ and rotary speed of 60 r/min by 80.3%.
【CateGory Index】: TG174.42
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