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《Materials Review》 2005-08
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Shape Effect on the Thermodynamic Properties of Metallic Nanoparticles

QI WeihongSchool of Materials Science and Engineering,Jiangsu University,Zhenjiang 212013;School of Materials Science and Engineering,Central South University,Changsha 410083WANG Mingpu School of Materials Science and Engineering,Central South University,Changsha 410083  
The thermodynamic properties of metallic nanoparticles not only depend on the particle size,but al- so depend on the particle shape.The shape effect model of metallic nanoparticles,developed by the author,is intro- duced in this paper.The model can predict the shape dependent cohesive energy,melting temperature,superheating, melting entropy,melting enthalpy,vacancy formation energy,vacancy concentration and phase diagram of nanoparti- cles.The present predictions agree with the corresponding experimental results.
【Fund】: 国家自然科学基金(No.50401010)
【CateGory Index】: TB383.1
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