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《Materials Review》 2005-08
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Study on Process of Thermodynamics for Chiral Separation of Naproxen in Molecular Imprinting

JIAO Feipeng HUANG Kelong YU Jingang PENG Xiahui ZHAO Xuehui NING Fengrong (College of Chemistry and Chemical Engineering,Central South University,Changsha 410083)  
A chiral stationary phase for the enantioselective separation of naproxen can be prepared by molecu- lar imprinting,in which 4-vinylpyridine(functional monomer)and trimethylol propane trimethacrylate are copolymer- ized in the presence of S-naproxen.Racemic naproxen is efficiently resolved on the molecular imprinting polymer.Fur- thermore,different functional monomers,flow rate in the mobile phase,temperature of column are investigated.The thermodynamic parameters are estimated,it is found that enantioselective separation is enthalpy controlled.
【Fund】: 国家自然科学基金(20376085);; 湖南省自然科学基金(03JJY3020)
【CateGory Index】: TQ460.1
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