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《Material Science and Technology》 2005-02
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Studied on CaO -Al_2O_3 -SiO_2 system black decorated glass-ceramics

HE Feng,LOU Guang-hui,HAO Xian-cheng ( Key Laboratory of Silicate Materials Science and Engineering, Ministry of Education, Wuhan University of Technology, Wuhan 430070, China  
In order to study and prepare black decorated glass-ceramics, Fe2O3,Ni2O3and Co2O3 were used to be colour agent, the influence of colour agent content on colour of glass-ceramic decorated materials, sintering and crystallization properties were studied in this paper. XRD and SEM were used to analysis the structure of black decorated glass-ceramics. The rational colour agent sort, content and heat treatment institution were defined. The result showed that both Fe2O3, Co2O3and Fe2O3, Co2O3, Ni2O3, could be used as colour agent, black glass series and black glass-ceramics with clear pattern were prepared by using these colour agent. In 100 gram glass batches, the rational weight of colour agents are Fe2O33-5 g, Co2O30. 15-0. 25 g and Ni2O30. 2 -0.4 g.
【Fund】: 国家自然科学基金资助项目(50272043) 湖北省自然科学基金资助项目(2002AB077) 武汉理工大学硅酸盐材料教育部重点实验室基金资助项目(SYSJJ2002-08) 武汉理工大学校基金资助项目(2003XJJ013).
【CateGory Index】: TQ171.733
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