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《Rare Metal Materials and Engineering》 2007-S3
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Catalytic Synthesis of Acetals and Ketals with H_3PW_6Mo_6O(40)/TiO_2

Yang Shuijin Tong Wenlong (Hubei Key Laboratory of Bioanalytical Technique,Hubei Normal University,Huangshi 435002,China)  
A new environmental friendly catalyst,H_3PW_6Mo_6O_(40)/TiO_2 was prepared.The optimum conditions have been found,that is, mass ratio of m(TiO_2):m(H_3PW_6Mo_6O_(40))1/2.0,volume of water 30 mL,the reflux reaction time 2 h,and activated temperature 150℃. H_3PW_6Mo_6O_(40)/TiO_2 was used as catalyst in catalytic synthesis of acetals and ketals,namely cyclohexanone ethylene ketal,cyclohexanone 1,2-propanediol ketal,butanone ethylene ketal,butanone 1,2-propanediol ketal,2-pbeny(?),3-dioxolane,4-methyl-2-pheny(?),3-dioxolane, 2-propy(?),3-dioxolane,4-methyl-2-propy(?),3-dioxolane.Effects of n(aldehyde(ketone)):n(glycol),catalyst dosage and reaction time on yield were investigated.Optimal conditions were:n(aldehyde(ketone)):n(glycol)=1.0:1.4;mass fraction of catalyst to reactants,0.8%; reaction time,1.0 h and cyclohexane as water-stripped reagent,10 mL.Under these conditions,yield of cyclohexanone ethylene ketal, cyciohexanone 1,2-propanediol ketal,butanone ethylene ketal,butanone 1,2-propanediol ketal,2-pheny(?),3-dioxolane, 4-methyl-2-phenyl-1,3-dioxolane,2-propyl-1,3-dioxolane and 4-methyl-2-propyl-1,3-dioxolane were 81.3%,86.9%,53.0%,66.9%, 72.3%,79.0%,66.8%,76.9% respectively.
【Fund】: 国家自然科学基金项目(20471044);; 湖北省自然科学基金项目(2005ABA053)资助
【CateGory Index】: O623.51
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