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《CHINESE JOURNAL OF MATERIAL RESEARCH》 1998-02
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PROCHLORE PHASE AND DISTRIBUTION IN Bi_2O_3-ZnO-Nb_2O_5 SYSTEM

WANG Hong; WANG Xiaoli;YAO Xi(Electronic Materials Research Laboratory, Xi 'an Jiaotong University, Xi 'an 710049 )  
The pyrochlore structure and phase distribution in Bi2O3-ZnO-Nb2O5(BZN) system were investigated. According to the principles of the crystal chemistry of pyrochlore, the possible pyrochlore area in BZN system was selected for study. The samples were quenched after calcining to maintain their phase structures at high temperatures. The phase stucture and phase constitution were analyzed by X-ray diffraction (XRD) technology. The isothermal phase diagram at 1000℃ about tWo pyrochlore structures (cubic phase α and orthorhombic phase β) and the α-β biphase have been obtained. The mechanism of the α-β displacive phase transformation has also been discussed.
【Fund】: 国家“863”高技术新材料领域计划资助
【CateGory Index】: O614
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