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《Journal of Northeast Normal University (Natural Science Edition)》 2003-04
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Modified-poly(4-vinylpyridine)and structural characterization

ZHANG Jian-he (Editorial Department of Journal of Xinyang Normal University,Xinyang 464000,China)  
Poly(4-vinylpyridine)was synthesized through freedical polymerization in the presence of N_2Modified-poly(4-vinylpyridine)was obtained through introducing n-dodecyl or ethyl groups on the main chains of poly (4-vinylpyridine).Results of IR and UV-vis spectrum of products show that graft-ratio of modified-poly (4-vinylpyridine)is very high.The ~c curves of poly(N-ethyl-4vinyl pyridinium bromide)(QPVPE) and poly(N-dodecyl and -ethyl-4vinyl pyridinium bromide)(QPVPD) illustrate that the hydrophobic interaction of side group has more influence on structural properities of QPVPD.The hydrophobic groups of main chains of QPVPD can aggregate and microdomains(micecelles)were formed in aquesous solutions,which lead to compact configuration of main chains and lower intrinsic viscosity.
【Fund】: 国家自然科学基金资助项目(29574160);; 信阳师范学院重点资助项目(9713004)
【CateGory Index】: O633
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