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《Geotectonica Et Metallogenia》 2006-02
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TYPES OF GAS HYDRATES AND THEIR CHARACTERISTICS IN MARINE ENVIRONMENTS

SU Zheng 1,2,3 and CHEN Duofu 1, 2 (1. CAS Key Laboratory of Marginal Sea Geology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, GD 510640, China; 2. Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou, GD 510640, China; 3. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China)  
The hydrates in marine environment can be grouped into two categories, diffusion system and venting system, according to hydrate occurrences. The first type of hydrate occurs widely in the world. Water-hydrate (two-phase) only coexists in gas hydrate stability zone (GHSZ) where a thermodynamic equilibrium system occurs. Free gas occurs beneath the base of the GHSZ only, inducing a bottom simulation reflection (BSR) to indicate the base of the hydrate occurrence zone. The hydrate buries deeply beneath seafloor and shows a low concentration relatively. Its precipitation is controlled by methane solubility and diffusion in addition to temperature and pressure, and affected by gas compositions, pore water salinity, gas supply and conversion ratios of organic carbon to methane. But the second type of hydrate is related to the conduits, such as fault especially, and occurs in the whole GHSZ where water-hydrate-free gas (three-phase) coexists in the system, so demonstrating no BSR in seismic section. This system is a thermodynamic unequilibrium system, and the hydrate accumulation is controlled by kinetics. This type of hydrate occurs in shallow water and shows a high concentration. Furthermore, a series of special phenomena in terms of geology, geophysics, geochemistry and biology arising from the activities of gas seeping occur in the sediments and in the overlying water column.
【Fund】: 中国科学院知识创新工程重要方向项目(KZCX3-SW-224);; 中国科学院知识创新工程前沿领域项目(GIGCX-04-03);; 国家自然科学基金项目(40572071)资助.
【CateGory Index】: P744.4
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