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《Geotectonica Et Metallogenia》 2009-04
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Geochemical Characteristics and Origin of A Manganese Deposit in the Middle Permian Maokou Formation in Shuicheng,Guizhou,China

YANG Ruidong,CHENG Mali and WEI Huairui (MOE Key Laboratory of Karst Environment and Geohazard Prevention,Guizhou University,Guiyang 550025,Guizhou,China)  
A new manganese deposit in the Middle Permian Maokou Formation in Shuicheng County,Guizhou Province,China was discovered. Study on trace elements of the manganese deposit shows that Cu,Zn,Ni,Co,As,Sb,Sr,Ba,Ga,Ag,V,U is enriched in the manganese deposit. The content of manganese is higher when the ratio of Th/U is lower than 1,and lower when the ratio of Th/U is 4~5. At the same time,Co/Ni values are lower than 1 in the manganese deposit.The plot of ∑Fe/Ti versus Al/(Al+Fe+Mn) shows that all samples located at the hydrothermal sediment area. (Fe+Mn)/Ti ratio values of the manganese deposit are high,up to 47~300,especially,(Fe+Mn)/Ti ratio values of the manganese deposit are higher,up to 300 in the higher Mn samples. The rock or manganese deposit was considered hydrothermal sedimentation when (Fe+Mn)/Ti ratio values is higher than 20,and Al/(Al+Fe+Mn) ratio values are low to 0.35. Al/(Al+Fe+Mn) ratio values of the manganese deposit present about 0.02 in the higher Mn samples. Therefore,ratio values of (Fe+Mn)/Ti and Al/(Al+Fe+Mn) show that the manganese deposit was formed under a hydrothermal sedimentary environment. Additionally,the higher ∑REE (mean 168×10-6),the lower ratio of LREE/HREE,negative Eu anomalies,and few remarkable positive Ce anomalies (except y-16,y-22) is similar to those of the Emeishan basalt. The geochemical characters of the manganese deposit above-mentioned suggest that manganese mineralization was affected by hydrothermal process of mantle plumes.
【Fund】: 贵州省科学基金;; 贵州省长基金;; 贵州省高层次人才基金;; 博士点建设项目联合资助
【CateGory Index】: P618.32
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