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《Chinese Geology》 2004-01
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Discovery of the complete isomorphous series of ZnS-CdS in nature and its preliminary study

LIU Tie-geng,ZHANG Qian,YE Lin,SHAO Shu-xun (Open Laboratory of Geochemistry of Mineral Deposits,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang550002,Guizhou,China)  
It was considered before that Cd can only limitedly substitute Zn in sphalerite in nature.However,in the recent study of the relationships between Cd and Zn in the Nujiaotang cadmium-zinc deposit,Guizhou,using the electron microprobe,scanning electron microscope and transmission electron microscope,the authors have found that Cd in zinc sulfide mainly exists as an isomorphous element with its content ranging from0.8%to37.93%,and that likewise Zn in cadmium sulfide also mainly exists as an isomorphous element with its content ranging from2.43%to38.64%.Zinc sulfide and cadmium sulfide show gradational relationship,and there is a good negative correlation between Zn and Cd with a correlation coefficient of0.99,forming a ZnS-CdS complete isomorphous series.This discovery has great theoretical significance and practical value not only in mineralogy but also in geochemistry and geology of mineral deposits.
【Key Words】： zinc cadmium ZnS-CdS mineral series isomorphism Cd-Zn deposit Guizhou
【Fund】： 国家自然科学基金项目(40172037);; 中国科学院矿床地球化学开放实验室基金项目资助。
【CateGory Index】： P578
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