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《Geochimica》 1992-03
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TETRAD EFFECTS OF RARE-EARTH ELEMENTS IN RARE-METAL GRANITES

Zhao Zhenhua(Institute of Geochemistry, Academia Sinica, Guangzhou 510640)Akimasa Masuda M. B. Shabani(Chenistry Department, Faculty of Sciences, Tyoko University, Japan)  
Described in this paper are the characteristics of tetrad effects of REE in raremetal granites. Based on the analytical data and experimentally geochemical data available, it is pointed out that the tetrad effects of REE in the granites are produced in the melt-fluid system. Intense fractional crystallization of granitic melt (containing REE accessories) and its interaction with volatile-rich (F, Cl) fluid are the major factors leading to the tetrad effects of REE. From this, the present paper presents a composite genetic model for high-degree fractional crystallization-volatile-rich fluid metasomatism of rare-metal granites. With the model, quantitative calculations have been made. Meanwhile, it is pointed out that the tetrad effects of REE can be used as an important indicator to distinguish mineralized granites from barren ones.
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