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《Geochimica》 2000-06
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Geochemistry of mineralizing fluid of Cd-rich zinc deposit: Taking Niujiaotang Cd-rich zinc deposit, Duyun, Guizhou for example

YE Lin1,2, LIU Tie-geng1, SHAO Shu-xun1 (1. Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China; 2. State Key Laboratory for Research of Mineral Deposits, Nanjing University, Nanjing 210093, China)  
Some organic inclusions were found in Niujiaotang Cd-rich zinc deposit, Duyun, Guizhou Province. The results show that this deposit is of Na++ Ca2+-Mg2+-Cl-system, which is similar to the MVT deposit, but different in temperature, salinity and density of mineralizing fluid. Except high contents of Ca2+ and Mg2+ , the compositions of the mineralizing fluid are similar to those of the oil-field brine. This may be related to the later carbonation stage. It is suggested that the mineralizing fluid may be have some relationship with the oil-field brine of Majiang paleo-oil pool. The mixing of oil-field brine containing mineralizing elements, such as Cd and Zn, with the low temperature and salinity fluid enriched in Ca2+ and Mg2+ resulted in the deposit, enrichment and mineralization of Cd and Zn, and formed calcite and dolomite in the ore area. From the early mineralizing stage to the later stage, the fO2 and pH of mineralizing fluid rose gradually, showing that the characters of the mineralizing fluid is on the alkalescence side and feeble deoxidize. The mineralizing fluid, which contains high and Cl-and with Cl-F-, Na+ K+ , was derived from oil-field brine, and the mineralizing elements transported and migrated as complexes of HS-and Cl-and organic complex.
【Fund】: 国家自然科学基金重点资助项目! (49633110);; 南京大学内生金属矿床成矿机制研究国家重点实验室基金资助项目;; 中国科学院矿床地球化学
【CateGory Index】: P592
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