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《Geochimica》 2002-06
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Origin of H_2S in Triassic Feixianguan Formation gas pools,Northeastern Sichuan Basin,China

WANG Yi-gang 1 ,DOU Li-rong 2 ,WEN Ying-chu 1 ,ZHANG Jing 1 ,LIU Hua-yi 1 (1.Research Institute of Exploration a nd Development,PetroChina Southwe st Oil and Gas Field Company,Chengdu610051,China;2.Research Institute of Petroleum Exploration and Development,CNPC,Beijing100083,China)   
The Triassic Feixianguan Formation sour gas pools at the Xuanhan-Kaixia n area in northeastern Sichuan Basin are buried to a depth of 3000~4500m presently,undergo temperature s of about 100℃and contain12%~17%H 2 S,75%~88%CH 4 .The H 2 S in the study area is formed by thermo chemical sulphate reduction(TSR)of the anhydrite underlying the gas r eservoirs.The statisticalδ 34 S values of the anhydrite,H 2 S,S°and FeS 2 ,associated with TSR,are +30.4‰,+12.9‰,+19.1‰,+19.4‰.Theδ 13 C andδ 18 O of the equant calcite partially replacing anhydr ite nodule is -7.26‰and -6.41‰.The h omogenization temperature of aque-ous fluid inclusions in the equant ca lcite ranges from 109℃to 151℃.The hi ghest burial temperature of the Feixianguan Formation in the study a rea was higher than 180℃,but the burial time was less than 20Ma when the burial temperature was greater than140℃as last tectonic uplift and denudaiton,so the H 2 S content is less than20%in the pools at the study area.
【Fund】: “九五”国家重点科技攻关项目(99-110-02-01);; 中国科学院广州地球化学研究所有机地球化学国家重点实验室基金资助项目;; 中国石油天然气集团公司青年创新基金项目“典型海相古生界油藏的形成、调整和重建”课题资助。
【CateGory Index】: P618.13
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