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《Geochimica》 2005-05
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Geological and geochemical characteristics of water-rock interaction in the processes of uranium mineralization in Zhuguang-Xiazhuang uranium ore-concentrated district

ZHANG Zhan-shi1,2, HUA Ren-min1, DENG Ping3, ZHU Ba3, WU Lie-qin3, ZHANG Yan-chun3, TAN Zheng-zhong3, YIN Zheng-ping3 1. State Key Laboratory for Mineral Deposit Research, Nanjing University, Nanj ing 210093, China; 2. Department of Geosciences and Geomatics, East China Institute of Technology , Fuzhou 344000, China; 3. Research Institute No.290, China National Nuclear Corporation, Shaoguan 512 026, China  
Zhuguang-Xiazhuang area is the biggest granitic-type uranium ore - concentrated district in China. Alteration of granites, tetrad effects of rare e arth element (REE) in granite and minerals, carbon, oxygen and strontium isotope s in calcite are employed to evaluate the characteristics of water-rock interac tion (WRI) in the processes of uranium mineralization. The results show that int ensive alteration developed in the granites is the direct exhibition of WRI. Cor rosions exhibited on the surface of uraninite reveal the activation of the urani um in the granite. Fission-track results show that chloritization is one of the important reactions to reactive the uranium in the granite occurred in the form of isomorphism. Conjugated M-and W-types of tetrad effects of REE simultaneou sly observed in the granite and minerals show that the fluid-granite interactio n is the key uranium ore-forming process in the Zhuguang-Xiazhuang uranium ore -concentrated district; the mineralization hosted granite rocks and the tourmal inite in granite shown M-type tetrad effects, while pitchblende, chlorite, illi te, calcite and pyrite shown W-type or W-M mixed type tetrad effects. It might infer that pitchblende was deposited from the fluid. Carbon, oxygen and stronti um isotopic values in calcite, especially the negative correlation between oxyge n and strontium isotope, might infer the mantle derived carbon, part of the prec ipitation origin of water and epidermis uranium.
【Fund】: 国家重点基础研究发展计划项目(1999CB403209);; 国家自然科学基金重点项目(40132010);; 国家自然科学基金(40472147)~~
【CateGory Index】: P619.14;
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