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《Geochimica》 2007-04
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Experimental study on distribution of Sn, Fe, W, Pb and Zn between granite magma and coexistent fluid at 850 ℃ and 400 MPa

WANG Yu-rong1, H.T. Hoselton2 and I-Ming Chou21. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;2. 954 National Center, U.S. Geological Survey, Reston, VA 20192, USA  
The influences of the F/Cl ratio on the entrance of Sn, Fe, W, Pb and Zn into supercritical thermal fluid in the processes of granite magma evolution are experimentally explored. The experiments are carried out with a big heating container (Harwood Engineering Co. Inc.) and the samples are natural granites. Experimental conditions: temperature is 850 ℃, pressure is 400 MPa, =2.1×10-13 (NNO), keep constant temperature for 120-128 h, solid/liquid≈1, the solid sample mass is about 250 mg, pressure medium is Ar. The results of the experiments show that the influence of ratio F/Cl on the distribution coefficient of W is slight, but the distribution coefficients of other elements all increase with increasing concentration of Cl and there is a sequence: . It is usually considered that the stability of Sn4+is closely dependent on F; however, our experiments show that Sn2+is more stable and its stability is dependent on Cl. Many mineralization elements are enriched in the glass scraps that are deposited on the wall of gold-pipe in process of quick quenching; glass enclosure and salt enclosure are also found.
【Fund】: 国家自然科学基金(40203006)
【CateGory Index】: P588.121;P595
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