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《Geochimica》 2009-04
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Geochemical characteristics of main ion and Sr isotope in the main channel of Xijiang River,South China

WANG Bing1,2, LEE Xin-qing1 , YUAN Hong-lin2, ZHOU Hui1,3 and ZHAO Yan-long4 1. State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China;2. State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710006, China;3. Graduate University of Chinese Academy of Sciences, Beijing 100049,China;4. The Pearl River Water Environment Monitoring Center, Guangzhou 510611, China  
Strontium geochemistry in surface waters helps shed light on regional hydrogeochemical characteristics and rock weathering rates in draining basins, as well as on anthropogenic influences to the environment. The analysis of Sr isotope ratios in rivers, therefore, has long been an interesting subject to geochemists. In this study, the 87Sr/86Sr ratios and the concentration of dissolved Sr and major anions and cations were measured in 19 water samples from the main channel of Xijiang and its tributaries in south China. The data indicates that the chemical ion composition of the river water is characterized by dominance of Ca2+ , Mg2+ ,HCO3- , and SO42-, which account for more than 80% of total anions and cations concentration, respectively.The sample water collected from the main tributary of Xijiang river has lower Sr concentration and higher Sr isotope ratios. By contrast, most of the water samples have higher Sr concentration and lower Sr isotope ratios, ranging from 0.0667 mg/L to 0.187 mg/L, and from 0.70856 to 0.70936, respectively. Compared to the world average concentration 0.078 mg/L and isotope ratios (87Sr/86Sr=0.7119), waters in the main channel of Xijiang have higher Sr concentrations and lower 87Sr/86Sr ratios. Weathering of limestones in the drainage basins is responsible for the high Sr concentrations, whereas the weathering of clastic rock is responsible for the Sr geochemistry in Yujiang. Our data also indicate that acid deposition and anthropogenic activities in the upper and middle region is responsible to the pollution in the main stream of Xijiang. By contrast, Yujiang is much less polluted.
【Key Words】： Sr rock weathering climate change water chemistry water pollution Xijiang
【Fund】： 中国科学院创新团队国际合作伙伴计划项目;; 国家自然科学基金(40403010);; 西北大学大陆动力学国家重点实验室开放课题基金(07LCD13)
【CateGory Index】： P597
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