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《Journal of Daqing Petroleum Institute》 1995-03
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INVESTIGATION ON REACTION CONDITION OFnC_5 ISOMERIZATION OVER NON-NOBLE BIMETAL CATALYST

WANG Guangwei, Associate Professor Dept of Petrochemical Engineering, Daqing Petroleum Institute, 151400, Anda, Heilongjiang, P. R. China LI Fengrong, MA Chunxi, SUN Xuewen Dept of Petrochemical Engineering  
The isomerization of normal pentane is carried out at 270-320°C , SV 0. 2-2. 5 h-1, H2/oil (molar ratio) 2. 0-6. 0, and pressure 1. 4-4. 0 MPa. The effect of single factor on the reaction is studied first. Then, by means of orthogonal design expriment, the optimum condition is obtained, i. e. conversion 0. 675 4, selectivity 0. 975 0, yield of C5+ iso-paraf-fins 0. 638 3, liquid yield of C5+ 0. 965 0 at 300°C, pressure 3. 0 MPa, SV 1. 0 h-1, and H2/oil 4. 0. The stability of the non-noble bimetal catalyst is examined in a 100 mL scale fixed bed reactor over a contiuous run of 1 000 hours, and the result shows that the stability of the catalyst is satisfactary.
【Fund】: 石油天然气总公司“八·五”科研攻关课题
【CateGory Index】: O643.3
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