Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Advances in Earth Science》 2008-04
Add to Favorite Get Latest Update

The Generation Synchroneity of H2S and C_(2+) Gaseous Alkane——Implications of Some Simulation Experiments

ZHANG Jianyong1,2,LIU Wenhui1,3,Tenger4,WANG Xiaofeng1,QING Ying5,MA Fengliang6(1.Lanzhou Oil-Gas Resource Centre,Institute of Geology and Geophysics,CAS,Lanzhou 730000,China;2.Graduate University,CAS,Beijing 100039,China;3.Exploration & Production Research Institute,SINOPEC,Beijing 100083,China;4.Wuxi Reseurch Institute of Petroleum Geology,SINOPEC,Wuxi 214151,China;5.Research Institute of Exploration and Development,Jidong Oilfield,Tangshan 063004,China;6.PetroChina Exploration & Development Research Institute(Northwest),Lanzhou 730020,China)  
The thermochemical sulphate reduction(TSR) is believed to be the determinative factor for gas reservoirs to generate high content of H2S(the volume percent of H2S above 5%),but the main hydrocarbon compounds react with sulphate are still not distinctly made sure.In this paper,based on the contrast analysis of TSR reaction systems(wet gas and magnesium sulfate,methane and calcium sulphate,heavy hydrocarbon and magnesium sulfate),through the analysis of TSR chemical equations and study of chemical kinetics and chemical thermodynamics,combined with geologic information,it is concluded that methane is believed to be the product of the TSR reaction between heavy hydrocarbon and sulphate,and not main reactant;there is synchroneity between the TSR reaction and the increasing of C2+ gaseous Alkane,the TSR reaction rate increase as C2+ Gaseous Alkane increase and the volume of H2S almost not increase till the wet gas cracked to be dry gas and then dry gas with H2S is generated.According to the analysis of oil and gas evolution stage,it is believed that TSR mainly at the stage of condensate gas generation by thermal cracking.When crude oil being cracked to be natural gas with H2S,the pressure system is changed and gas with H2S will be newly accumulated and the natural gas with H2S will be accumulated again in new traps if the structural environment changes.So,the volume of H2S in natural gas reservoirs is not only controlled by generation conditions but by other factors,such as migration pathway conditions,reservoirs conditions and preservation conditions.
【CateGory Index】: P618.13
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 ZHANG Jian-yong1,2,LIU Wen-hui2,3,4,TENGER4,WANG Xiao-fang1,ZHANG Jingyi5(1.Hangzhou Research Institute of Petroleum Geology,Hangzhou 310023,China;2.Research Center of Oil and Gas,Institute of Geology and Geophysics,Chinese Academy of Sciences,Lanzhou 730000,China;3.Exploration & Production Research Institute,SINOPEC,Beijing 100083,China;4.Wuxi Institute of Geology,Exploration & Production Research Institute,SINOPEC,Wuxi 214151,China;5.Research Institute of Exploration and Derelopment,Jidong Oilfield,Tangshan 063004,China);Characteristics of Natural Gas in P_2ch—T_1f Layers in Jiannan Gas Field and Gas Source Correlation[J];Natural Gas Geoscience;2010-06
【Citations】
Chinese Journal Full-text Database 10 Hits
1 Dai Jinxing ( Scientific Research Institute of Petroleum Exploration and Development, Beijing);DISTRIBUTION, CLASSIFICATION AND ORIGIN OF NATURAL GAS WITH HYDROGEN SULPHIDE IN CHINA[J];Acta Sedimentologica Sinica;1985-04
2 YUE Chang tao LI Shu yuan DING Kang le ZHONG Ning ning (State Key Lab of Heavy Oil Processing, School of Chemical Engineering, University of Petroleum, Beijing 102249);The Formation of Ferric Sulfide in the TSR System for the Carbonate Rock[J];Acta Sedimentologica Sinica;2004-04
3 ZHU Guang-you~ 1 ZHANG Shui-chang~ 1 LIANG Ying-bo~ 1 MA Yong-sheng~ 2 ZYOU Guo-yuan~ 3 DAI Jin-xing~ 1 (1.Research Institute of Petroleum Exploration and Development, China National Petroleum Corporation, Beijing100083; 2.Institute of Southern Exploration and Development Division Company of SINOPEC,Kunming 650200; 3.East Sichuan Drilling Co.Ltd,Sichuan Petroleum Administration, Chongqing 400021);Characteristics of Gas Reservoirs with High Content of H_2 S in the Northeastern Sichuan Basin and the Consumption of Hydrocarbonsdue to TSR[J];Acta Sedimentologica Sinica;2006-02
4 WANG Yi-gang 1 ,DOU Li-rong 2 ,WEN Ying-chu 1 ,ZHANG Jing 1 ,LIU Hua-yi 1 (1.Research Institute of Exploration a nd Development,PetroChina Southwe st Oil and Gas Field Company,Chengdu610051,China;2.Research Institute of Petroleum Exploration and Development,CNPC,Beijing100083,China) ;Origin of H_2S in Triassic Feixianguan Formation gas pools,Northeastern Sichuan Basin,China[J];Geochimica;2002-06
5 YUE Chang-LI Shu-yuan, DING Kang-le, ZHONG Ning-ning (State Key Lab of Heavy Oil Processing, University of Petroleum, Beijing 102249, China);Simulation experiments on thermochemical sulfate reduction of methane with solid calcium sulfate[J];Geochimica;2003-06
6 YU Lin-ping, PAN Chang-chun, LIU Jin-zhong, FU Jia-mo(State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China);Influence of oxidation by minerals on proportional and carbon isotopic compositions of gaseous hydrocarbons[J];Geochimica;2005-03
7 CAI Chun-fang,LI Hong-tao(Key Labortory of Mineral Resources,Institute of Geology and Geophysics,CAS,Beijing 100029,China);THERMOCHEMICAL SULFATE REDUCTION IN SEDIMENTARY BASINS:A REVIEW[J];Advance in Earth Sciences;2005-10
8 Zhao Mengjun Lu Shuangfang1) Research Institute of Petroleum Exploration and Development of CNPC, Beijing, 100083 2) Department of Exploration, Daqing Petroleum Institute, Anda City, 151406;Natural Gas from Secondary Cracking of Crude Oil ——An Important Pattern of Gas Generation[J];Geological Review;2000-06
9 ZHANG Shuichang, ZHU Guangyou, LIANG Yingbo Research Institute of Petroleum Exploration and Development, PetroChina, Beijing, 100083;Probe into Formation Mechanism of H_2S and High-quality Reservoirs of Puguang Large Gas Field in Sichuan Basin ——The New Cognition after Reading Professor Ma's Paper “Discovery of the Large-scale Gas Field in the Sichuan Basin and Its Enlightenment for[J];Geological Review;2006-02
10 MA Yongsheng, CAI Xunyu, LI GuoxiongSouthern Exploration & Development Division Company of SINOPEC, Kunming, 650200;Basic Characteristics and Concentration of the Puguang Gas Field in the Sichuan Basin[J];Acta Geologica Sinica;2005-06
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Jiazhen,XU Bei,PANG Xuyong,WEI Wei,WANG Yu The Key Laboratory of Orogenic Belts and Crustal Evolution,Ministry of Education,School of Earth and Space Sciences,Peking University,Beijing 100871;;Organic Geochemistry of Nanmingshui Formation Source Rocks in Shaerbulake Region,Fuyun County,Xinjiang[J];Acta Scientiarum Naturalium Universitatis Pekinensis;2009-02
2 LI Duoli GUAN Ping (School of Earth and Space Sciences ,Peking University, Beijing, 100871);Research Situation and Prospect of Hydrocarbon Migration in China[J];Acta Scicentiarum Naturalum Universitis Pekinesis;2004-04
3 ZHANG Tingting~1, LIU Bo~ 2,QIN Shan~1 ~1School of Earth and Space Sciences,Peking University, Beijing 100871; ~2Institute of Oil and Gas,Peking University, Beijing 100871;The Origin of Permian and Triassic Dolostones in Northeastern Sichuan Province,China[J];Acta Scientiarum Naturalium Universitatis Pekinensis;2008-05
4 WAN Xiao-long~(1,2),QIU Nan-sheng~2,SHI Shuo~3,ZENG Jian-hui~2 (1. Research Institute of Exploration and Development, Changqing Oilfield Companlation, Ministry of Education, University of Petroleum, Beijing102249,China; 3. Changqing Oilfield Company, Xi'an710021,China);Mechanism of fullness degree of lithologic reservoirs in over-pressure system in Dongying sag[J];Journal of Jiling University (Earth Science Edition);2004-03
5 WANG Yong-quan,XIONG Yong-qiang,WANG Yan-meiGuangzhou Institute of Geochemistry/State Key Laboratory of Organic Geochemistry,CAS,Guangzhou 510640,China;Organic Geochemical of Solid Bitumen from the Northeastern Sichuan Basin[J];Journal of Jilin University(Earth Science Edition);2008-01
6 NIU Jian-jun,ZHANG Xiao-pei,DU Li-zhiCollege of Construction Engineering,Jilin University,Changchun 130026,China;The Potential Monitoring Technique During Inject Steam to Drive Thick Oil[J];Journal of Jilin University(Earth Science Edition);2008-05
7 GAO Mei-sheng1,ZHENG Rong-cai1,WEN Hua-guo1,LI Lian-xin2,LI Hong21.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China;2.Research Institute of Exploration and Development,Changqing Oil-field Company of CNPC,Xi'an 710021,China;3.Chongqing Gas District of Southwest Oil and Gas Company of CNPC,Chongqing 400021,China;Lithological characteristics of dolomite in the Lower Triassic Feixianguan Formation of the NE Sichuan Basin,China[J];Journal of Chengdu University of Technology(Science & Technology Edition);2007-03
8 HUANG Si-jing,WANG Chun-mei,HUANG Pei-pei,ZOU Ming-liang,WANG Qing-dong,GAO Xiao-yongState Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China;Scientific research frontiers and considerable questions of carbonate diagenesis[J];Journal of Chengdu University of Technology(Science & Technology Edition);2008-01
9 GENG Wei1,ZHENG Rong-cai1,LI Shuang2,LI Gui-li2,ZHENG Chao2,HU Zhong-gui11.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China;2.Chongqing Gas Department of Southwest Oil and Gas Subsidiary Company,CNPC,Chongqing 400021,China;Characteristics of reservoirs of Upper Permian Changxing Formation in the eastern Kaijiang-Liangping intraplatform trough in Sichuan,China[J];Journal of Chengdu University of Technology(Science & Technology Edition);2008-06
10 LIN Liang-biao,CHEN Hong-de,ZHU Lidong,XU Sheng-lin, HAO Yi,ZHONG Yi-jiang State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China;Sedimentary characteristics and sequence stratigraphy of the Middle-Upper Permian in Shizhu,Chongqing,China[J];Journal of Chengdu University of Technology(Science & Technology Edition);2008-06
China Proceedings of conference Full-text Database 5 Hits
1 Changtao Yue, Shuyuan Li State Key Lab of Heavy Oil Processing, University of Petroleum, Beijing 102249, China;Study of the kinetics on the TSR system[A];[C];2005
2 WAN Zhifeng,CAI Zhourong,LIANG Zhengzhong,LIU Weiliang, LUO Jiwen,GAO Huijun (Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,China; Graduate University of Chinese Academy of Sciences,Beijing 100049,China);Characteristics of Formation Pressure in Chexi Sag,Bohaiwan Basin[A];[C];2009
3 LUO Xiao-rong (Institute of Geology and Geophysics of Chinese Academy of Sciences,Beijing 100101,China);REVIEW OF HYDROCARBON MIGRATION AND ACCUMULATION DYNAMICS[A];[C];2003
4 CAI Chun-fang~1,WU Guang-hui~2,LI Kai-kai~1,CHEN Li-xin~2,LI Mei~2,LI Hong-tao~1 1.Key Laboratory of Mineral Resources,Institute of Geology and Geophysics,Chinese Academy of Sciences, Beijing 100029,China;2.Tarim Oil field Company,PetroChina,Kuerle,Xinjiang 841000,China;Thermochemical Sulfate Reduction and Origin of Sulfur in Crude Oils in Palaeozoic Carbonates[A];[C];2008
5 Sun Dongsheng,Li Tiejun,Zhang Yanfang;Achievement and Prospect of Petroleum and Natural Gas Geology[A];[C];2006
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 SU Fang\ SHAO Min\ ZHANG Min (State Joint Key Laboratory of Environmental Simulation & Pollution Control, Center for Environmental Sciences,Peking University,Beijing,100871);Trends and Spatial Distributions of Methane Emissions in Beijing[J];Acta Scicentiarum Naturalum Universitis Pekinesis;2002-04
2 LIANG Xi-wen~(1,2),ZHENG Rong-cai~(1,2),ZHANG Tao~3,LIN Juan-hua~31.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China;2.Institute of Sedimentary Geology,Chengdu University of Technology,Chengdu 610059,China;3.The Research Institute of Petroleum Exploration & Development of Jianghan Oilfield Company,Qianjiang 433124,China;Accurate sequence stratigraphy and reservoir assessment of point reefs and shoals in the Late Permian Changxing Formation of the Jiannan structure,Lichuan,Hubei,China[J];Journal of Chengdu University of Technology(Science & Technology Edition);2006-04
3 YANG Jia-jing~1 WANG Yi-gang~1 WANG Lan-sheng~1 WEN Ying-chu~1 LIU Hua-yi~1 Zhou Guo-yuan~2 1(Institute of Exploration and Development, Southwest Oil and Gas Field Branch Company, PetroChina, Subkey Laboratory of Carbonate Gas Reservoir Formatio;The Origin of Natural Gases and Geochemistry Characters ofChangxing Reef and Feixianguan Oolitic Beach Gas Reservoirs in Eastern Sichuan Basin[J];Acta Sedimentologica Sinica;2002-02
4 WEI Guo-qi~ 1CHEN Geng-shen~ 2YANG Wei~ 1YANG Yu~ 2HU Ming-yi~ 3 ZHANG Li~ 1WU Shi-xiang~ 1JIN Hui~ 1SHEN Jue-hong~ 1 1( Gas Department, Langfang Branch, Research Institute of Petroleum Exploration and Development, CNPC, LangfangHebei065007) 2(West-south Oilfield Brand, Chengdu610051) 3(Jianghan Petroleum Institute, Jinzhou Hubei434102);Sedimentary System of Platformal Trough of Feixianguan Formation of Lower Triassic in Northern Sichuan Basin and Its Evolution[J];Acta Sedimentologica Sinica;2004-02
5 Shen Ping Xu Yongchang(Bio geochemistry and Gasgeochemistry Laboratory, Lanzhou, Institute of Geology, Academia Sinica, Lanzhou, 730000);THE ISOTOPIC COMPOSITION OF NATURAL GASES FROM CONTINENTAL SEDIMENTS IN CHINA[J];Geochimica;1991-02
6 Liu Wenhui Xu Yongchang(State Key Laboratory of Gas Geochemistry,Lanzhou Institute of Geology,Chinese Academy of Sciences, Lanzhou 73000);A two stage model of carbon isotopic fractionation in coal gas[J];GEOCHIMICA;1999-04
7 WANG Yi-gang 1 ,DOU Li-rong 2 ,WEN Ying-chu 1 ,ZHANG Jing 1 ,LIU Hua-yi 1 (1.Research Institute of Exploration a nd Development,PetroChina Southwe st Oil and Gas Field Company,Chengdu610051,China;2.Research Institute of Petroleum Exploration and Development,CNPC,Beijing100083,China) ;Origin of H_2S in Triassic Feixianguan Formation gas pools,Northeastern Sichuan Basin,China[J];Geochimica;2002-06
8 Wang Dongmei , Hao Yuexing & Zhu Lei (E&D Research Institute of Daqing Petroleum Administrative Bureau, Heilongjiang,163712, P. R. China) .;ANALYSIS ON REASONABLE WELL PATTERN AND SPACING OF ASP FLOODING[J];PETROLEUM GEOLOGY & OILFIELD DEUELOPMENT IN DAQING;1999-03
9 LIU Qiang, WANG Yue-Si, WANG Ming-Xing, LI Jing, and LIU Guang-RenInstitute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029;Trends of Greenhouse Gases in Recent 10 Years in Beijing[J];Chinese Journal of Atmospheric Sciences;2005-02
10 MA Yongsheng, Guo Xusheng, Guo Tonglou, Huang Rui, CAI Xunyu, LI Guoxiong Institute of Southern Exploration and Development Division Company of SINOPEC, Kunming, 650023;Discovery of the Large-scale Puguang Gas Field in the Sichuan Basin and Its Enlightenment for Hydrocarbon Prospecting[J];Geological Review;2005-04
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Dai Jinxing ( Scientific Research Institute of Petroleum Exploration and Development, Beijing);DISTRIBUTION, CLASSIFICATION AND ORIGIN OF NATURAL GAS WITH HYDROGEN SULPHIDE IN CHINA[J];Acta Sedimentologica Sinica;1985-04
2 Ma Xiuzhen Yin Mingshan (Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou) Wang Dazhen ( Institute of Microbiology, Academia Sinica, Beijing );SULFATE-REDUCING BACTERIA AND THEIR GEOBIOCHEMICAL ROLE OF SALT LAKE SEDIMENTS OF CHINA[J];Acta Sedimentologica Sinica;1987-02
3 YANG Jia-jing~1 WANG Yi-gang~1 WANG Lan-sheng~1 WEN Ying-chu~1 LIU Hua-yi~1 Zhou Guo-yuan~2 1(Institute of Exploration and Development, Southwest Oil and Gas Field Branch Company, PetroChina, Subkey Laboratory of Carbonate Gas Reservoir Formatio;The Origin of Natural Gases and Geochemistry Characters ofChangxing Reef and Feixianguan Oolitic Beach Gas Reservoirs in Eastern Sichuan Basin[J];Acta Sedimentologica Sinica;2002-02
4 CHENXue-shi YIWan-xiaLU Wen-zhong (Hangzhou Institute of Petroleum Geology, CNPC,Hangzhou 310023);The Paleokarst Reservoirs of Oil/Gas Fields in China[J];Acta Sedimentologica Sinica;2004-02
5 WEI Guo-qi~ 1CHEN Geng-shen~ 2YANG Wei~ 1YANG Yu~ 2HU Ming-yi~ 3 ZHANG Li~ 1WU Shi-xiang~ 1JIN Hui~ 1SHEN Jue-hong~ 1 1( Gas Department, Langfang Branch, Research Institute of Petroleum Exploration and Development, CNPC, LangfangHebei065007) 2(West-south Oilfield Brand, Chengdu610051) 3(Jianghan Petroleum Institute, Jinzhou Hubei434102);Sedimentary System of Platformal Trough of Feixianguan Formation of Lower Triassic in Northern Sichuan Basin and Its Evolution[J];Acta Sedimentologica Sinica;2004-02
6 Xu Yongchang Wang Xianbin Wu Renming Shen Ping Wang Youxiao He Yongping;RARE GAS ISOTOPIC COMPOSITION OF NATURAL GASES[J];Geochimica;1979-04
7 Shen Ping Xu Yongchang(Bio geochemistry and Gasgeochemistry Laboratory, Lanzhou, Institute of Geology, Academia Sinica, Lanzhou, 730000);THE ISOTOPIC COMPOSITION OF NATURAL GASES FROM CONTINENTAL SEDIMENTS IN CHINA[J];Geochimica;1991-02
8 Liu Wenhui Xu Yongchang(State Key Laboratory of Gas Geochemistry,Lanzhou Institute of Geology,Chinese Academy of Sciences, Lanzhou 73000);A two stage model of carbon isotopic fractionation in coal gas[J];GEOCHIMICA;1999-04
9 WANG Yi-gang 1 ,DOU Li-rong 2 ,WEN Ying-chu 1 ,ZHANG Jing 1 ,LIU Hua-yi 1 (1.Research Institute of Exploration a nd Development,PetroChina Southwe st Oil and Gas Field Company,Chengdu610051,China;2.Research Institute of Petroleum Exploration and Development,CNPC,Beijing100083,China) ;Origin of H_2S in Triassic Feixianguan Formation gas pools,Northeastern Sichuan Basin,China[J];Geochimica;2002-06
10 LI Xian-qing 1,2 ,HU Guo-yi 1,3 ,LI Jian 3 ,ZHANG Ai-yun 4 ,HOU Du-jie 4 ,TANG You-jun 2 (1.Guangzhou Institute of Geochemistr y,Chinese Academy of Sciences,Guangzhou510640,China;2.Jianghan Petroleum University,Jingzhou434023,China;3.Institute of Natrual Gas Geology,Langfang Branch,Research Institute o f Petroleum Exploration &Development,CNPC,Langfang065007,China;4.China University of Geosciences,Be ijing100083,China);Geochemical indexes and evaluation of mixed origin natural gases from Central Gas Field in the Ordos Basin[J];Geochimica;2003-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved