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《Earth Science Frontiers》 2011-05
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Ore geology and ore-forming fluid geochemistry of Zhouzhuang Ag-Pb-Zn deposit,southwestern Henan Province

Cao Jihu1,Xiang Shihong1,2,Xue Chunji1,Zhang Xu2,Li Yongfeng2,Li Bingqi2,Cheng Wenhou2 1.State Key Laboratory of Geological Processes and Mineral Resources;School of Earth Sciences and Resources,China University of Geosciences(Beijing),Beijing 100083,China 2.Bureau of Non-ferrous Metals Geological and Mineral Resources,Zhengzhou 450016,China  
The Zhouzhuang Ag-Pb-Zn ore deposit was recently discovered in the southwestern Henan Province where there are some other Ag-Pb-Zn ore deposits.It occurred in an inter-plate tectonic-magmatic geological environment after Indosinian orogeny.The ore-body is mainly in the Erlangping Group and the veins of quartz-(Ag-Pb-Zn) sulfides filled in the fault fractures whose strike-directions are perpendicular to the orogenic belt.The Ag-Pb-Zn hydrothermal mineralization shows three stages: the early stage is characterized by quartz-pyrite;the main stage is quartz-(Ag-Pb-Zn) sulfide;and the late stage is quartz-calcite.Three types of fluid inclusions were trapped in the quartz in the Ag-Pb-Zn ores;they are the water solution,the CO2-H2O,and the daughter mineral-bearing inclusions.The ore-forming fluid temperatures of the early,the main and the late mineralization stages are 310-270 ℃,230-200 ℃,and 180-150 ℃,respectively.The ore-forming fluid salinity of the early stage is 10%-6% NaCleq.,the main stage is 18%-14% NaCleq.,and the late stage 12%-8% NaCleq..The temperature decreased,and the salinity increased first and then decreased during the mineralization.The mineralization were accompanied with the rising of the crust;the ore-forming fluid pressures in the early-,the main-and the late-mineralization stages are 270-235 MPa,230-200 MPa,and 79.39-39.37 MPa,respectively;and the corresponding depths are 10-8.7 km,8.5-7.4 km,and 2.9-1.5 km,respectively.The δDH2O V-SMOW decreased from-59‰——70‰ to-70‰——82‰ and the δ18OH2O V-SMOW also decreased from 5.19‰-6.53‰ to 2.32‰-2.46‰ when the mineralization developed from the early to the main stage,and the δ18OH2O V-SMOW further decreased to-0.05‰ in the late mineralization stage.The ore-forming fluid was mainly from the magma or the metamorphic water,and mixed by some meteoric water in the late stage.This study gives some new information for understanding the metallogeny of Ag-Pb-Zn in southwestern Henan Province.
【Fund】: 国家自然科学基金项目(41072069 40772061);; 地质过程与矿产资源国家重点实验室科学基金项目(GPMR0936);; 河南省有色金属地质矿产局科技创新项目(YSDK2010-6);; 河南省科技发展计划项目(2010-021)
【CateGory Index】: P618.2
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