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Synthesis of Zwitterionic AM/AMPS Copolymer as Filtrate Reducer for Drilling Fluid by Hofmann Reaction

WANG Yan-xin~a,CHEN Yan-ling~b,SONG Jun-ting~a(a.Graduate School;b.Faculty of Material Science and Chemistry Engineering,China University of Geosciences,Wuhan 430074,China)  
A kind of new zwitterionic copolymer was synthesised by using acrylamide(AM) and 2-acrylamido-2-methylpropane sulfonicacid(AMPS) as monomer.The process includes two steps: free radical copolymerization in water solution and partially Hofmann degradation.The paper discussed the effect of different reaction conditions on property of the product,characterized the coppolymer by IR,determinated the substitution(-NH+3) degree of the coppolymer by colloid titration,and evaluated the properties of mud containing the copolymer in laboratory.The experimental results show that zwitterionic AM/AMPS copolymer had very good capacity of depressing filter loss,heat resistance and salt tolerance.
【CateGory Index】: TE254.4
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