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《Acta Geologica Sinica》 2006-08
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Distribution of High H_2S-Bearing Natural Gas and Evidence of TSR Origin in the Sichuan Basin

ZHU Guangyou 1), ZHANG Shuichang 1), LIANG Yingbo 1), MA Yongsheng 2), GUO Tonglou 2), ZHOU Guoyuan 3) 1) Research Institute of Petroleum Exploration and Development, PetroChina, Beijing, 100083 2) Southern Exploration and Development Company, SINOPEC, Kunming, 650200 3) Geological Lab of East Sichuan Drilling Company, Sichuan Petroleum Administration, PetroChina, Chongqing, 400021  
The Sichuan Basin is the richest area in high H_2S-bearing natural gas in China. Presently, explored reserves of over 500 billion cubic meter of natural gas have been found, which lie in Sinian (Weiyuan gas field), the Feixianguan Formation of Lower Triassic (Luojiazhai, Puguang, Dukouhe, Tieshanpo and Qilibei gas fields), Jialingjiang Formation of Lower Triassic (Wolonghe gas field) and Leikoupo Formation of Middle Triassic (Moxi and Zhongba gas fields), including about 10 large and medium gas fields (pools) with high H_2S content. All the gas pools are buried in great depth (reservoir suffered high temperature), and the upper, lower or middle reservoirs have gypsiferous rock and sufficient hydrocarbon gas, so, the reservoirs possess material and dynamic conditions of thermochemical sulfate reduction (TSR). The geology of gas pools, natural gas components, carbon and sulfur isotopes indicate that the H_2S of Middle and Lower Triassic and Sinian gas pools are of TSR origin. Selective hydrocarbon depletion makes natural gas drier, and correspondingly the gas pool filling and pressure coefficient decrease.
【Fund】: 中国石油天然气股份公司科技项目(编号040502-10-01);; 国家重点基础研究发展规划项目(编号2001CB209100)资助成果
【CateGory Index】: P618.13
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3 WEI Yun-Jin~1,AI Jia-Wei~2,LUO Si-Lu~1 (1.Northwest Sichuan Environmental Monitoring Center,Petrochina Southwest Oil-Gas Field Company,Mianyang, Sichuan 621700,China;2.College of Chemistry & Chemical Engineering,Southwest Petroleum University,Chengdu 610500,China );The Hazardous Factors and Protective Measures of Hydrogen Sulfide for Gas Delivery Operation[A];[C];2012
4 CAI ChunFang,CAI LiuLu,ZHANG Jun,CAI XunYu and LI KaiKai 1.Key Lab of Petroleum Resources,Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,China 2.Department of Science and Technology,SINOPEC,Beijing 100728,China 3.Oilfield Department,SINOPEC,Beijing 100029,China;H_2S-generation by methane-dominated TSR and carbon isotope fractionation in Lower Triassic Feixianguan Formation,Northeast Sichuan Basin[A];[C];2013
5 Kaikai Li~a,Chunfang Cai~(a,*),Lei Jiang~a,Liulu Cai~(a,b),Lianqi Jia~a,Bing Zhang~c,Lei Xiang~a,Yuyang Yuan~a a Key Laboratory of Petroleum Resources Research,Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,China b National Engineering Lab.of Biohydrometallurgy,General Research Institute for Nonferrous Metals,Beijing 100088,China c State Key Lab Oil Gas Reservoir Geology and Exploitation,Institute of Sedimentary Geology,Chengdu University of Technology,Chengdu 610059,China;Sr evolution in the Upper Permian and Lower Triassic carbonates,northeast Sichuan basin,China:Constraints from chemistry,isotope and fluid inclusions[A];[C];2013
6 LI KaiKai,CAI ChunFang,CAI LiuLu,JIANG Lei and XIANG Lei Key Lab of Petroleum Resources Research,Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,China;Origin of sulfides in the Middle and Lower Ordovician carbonates in Tahe oilfield,Tarim Basin[A];[C];2013
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