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《Acta Geologica Sinica》 2009-02
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The Huangshan A-type granites with tetrad REE: constraints on Mesozoic lithospheric thinning of the southeastern Yangtze craton?

XUE Huaimin1), WANG Yinggeng2), MA Fang3), WANG Cheng4), WANG Deen2), ZUO Yanlong2) 1) Institute of Geology, Chinese Academy of Geological Sciences, Beijing, 100037; 2) 332 team, Bureau of Geology and Mineral Resources of Anhui Province, Huangshan, Anhui,245000; 3) School of Earth and Space Sciences, Beijing University, Beijing, 100871; 4) Department of programming and ground, world geological park of Huangshan, Anhui,245000  
The Huangshan granites are characterized by high SiO2 ( 75 %), low calcium CaO (0.51 ~ 0.86 %), poor MgO, relatively high alkali and high FeO*/MgO ratio (8.28 ~ 87.20). Geochemical analysis shows that the granites is extremyly depleted in Ba, Sr, and Eu (δEu = 0.01 ~ 0.13), rich in strong incompatible elements such as Rb, Th and U. The contents of high field strong elements such as Zr, Nb, Y and Ga are relatively high. Major and trace elements signature indicates that the Huangshan granites belong to A-type. The tetrad effect is presence in the granites' REE distribution diagrams. Some trace elements behavior can't be controlled by charge and radius of ions, such as, extremely low ratios of K/Rb and Zr/Hf and distinctly high K/Ba. The features can be observed only in highly evolved magma which strongly interactes with hydrothermal fluid. Compared with the calc-alkaline Taiping granitoids, the highly evolved Huangshan A-type granites have relatively low initial 87Sr/86Sr ratios (0.707,but 0.710 for the Taiping granitoids) and high εNd(t) values (-4.45 ~ -4.87,but -6.21~-6.40 for the Taiping granitoids). The two-stage model ages (TDM-2) for the Huangshan granites is 1.24 ~ 1.33Ga, clearly smaller than the model ages of the Taiping granitoids (1.44 ~ 1.45Ga), implying that a great deal of asthenospheric mantle material entered into the parent magma of the Huangshan granites. It is concluded that the change from the calc-alkaline Taiping granitoids to the alkaline Huangshan granites refers the Mesozoic lithospheric thinning of the southeastern Yangtze craton.
【Fund】: 中国地质调查局地质调查项目(编号1212010711814);; 安徽省财政专项(编号2003-39);; 国家自然科学基金项目(编号40503006、40472035、40772048)研究成果
【CateGory Index】: P588.121
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