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《Acta Geologica Sinica》 2015-02
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Characteristics and Source Significance of Trace Element Geochemistry of Fluorite from Chashan Sb-W Deposit in Guangxi

SHEN Nengping;CAI Jiali;SU Wenchao;DONG Wendou;State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences;University of Chinese Academy of Sciences;  
The Chashan Sb-W deposit is located in Dachang Sn-polymetallic ore field,Nandan,Guangxi.Fluorite is one of major gangue minerals in this deposit,which is closely related with antimony and tungsten mineralization.Geochemical study on trace elements(including rare earth elements,REE)of fluorite was carried out systematically in this paper.The results show that the total REE concentrations of fluorite range from 4.03×10-6 to 77.53×10-6,with an average of 38.72×10-6.The chondritenormalized REE distribution pattern is flat,with slight fractionation between LREE and HREE,and slightly Ce negative anomaly(δCe=0.76~0.87)and relatively strong Eu positive anomaly(δEu=1.48~2.94).These features are clearly different from the characteristics of REE(LREE-rich pattern,with obvious negative Eu anomaly)for different types of ores,host rocks and magmatic rocks from Dachang Snpolymetallic ore field.Furthermore,compared with other elemental abundance of the continental crust and Devonian strata in the western Guangxi,the fluorite from Chashan deposit is riched in Sb and W,and depleted in Cu,Zn,Co,Ni,etc.By comprehensive analysis and comparison the ore-forming fluid closed associated with Sb-W mineralization of Chashan deposit would not be sourced from the Devonian host rocks,may be derived dominantly from deep-circled fluids.
【Fund】： 国家重点基础研究发展计划973课题(编号:2014CB440904);; 国家自然科学基金项目(编号:41272113和40972072);; 矿床地球化学国家重点实验室“十二五”项目群(编号:SKLODG-ZY125-01)资助的成果
【CateGory Index】： P618.6
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