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《Journal of Fudan University》 2002-04
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The Preparation and Catalytic Behavior of Ru/ZrO_2·xH_2O in Benzene Selective Hydrogenation

WANG Jian qiang, XIE Song hai, CHEN Hai ying, HU Jian guo, FAN Kang nian, QIAO Ming hua (Molecular Catalysis & Innovative Material Laboratory, Department of Chemistry, Fudan University, Shanghai 200433, China)  
A novel benzene selective hydrogenation catalyst, Ru/ZrO 2· x H 2O, was prepared by a coprecipitation method. The structure and physico chemical properties of the catalyst were characterized by TEM and XRD,The influence of reduction treatment process of the catalyst to benzene selective hydrogenation was studied in detail. The influence of inorganic additive ZnSO 4·7H 2O, reaction conditions such as reaction temperature, stir speed etc. to the reaction of hydrogenation was also explored. It is found that the existence of ZnSO 4·7H 2O during the reduction treatment and at reaction temperature 145 ℃ with stir speed bigger than 800 r/min, the selective hydrogenation result was the best. The best gain of cyclohexene may reach 36.7%.
【Fund】: “973”国家重点基础研究发展规划资助项目 (G2 0 0 0 0 4 80 0 9);; 国家自然科学基金资助项目 (2 0 0 730 0 8);; 复旦青年基金资助课题
【CateGory Index】: O643.3
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