Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Fudan University》 2003-03
Add to Favorite Get Latest Update

The Photo-oxidation of COS

ZHANG Feng, WU Hongbo, XUE Huaxing, WU Beili, CHEN Jianmin(Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, China)  
The photooxidation of COS under the irradiation of ultraviolet light, has been studied in the COSO2 system. The reaction was explored through FTIR, White Cell, XPS and GCMS. The result showed that the major photooxidation products of COS under the irradiation of ultraviolet light were CO2 and SO2 in COSO2 system. SO42- was identified due to the further oxidation of SO2. The added O2 had a positive influence on the conversion of COS. With the increasing of O2, the apparent rate constants of photooxidation increased first, then the increament decreased gradually. The results indicated that the photooxidation of COS under irradiation of ultraviolet was apparent firstorder reaction. The apparent rate constant is 10-4-10-3 s-1.The experiment provides evidences for the photooxidation of COS in the atmosphere and the formation of sulfate aerosols.
【Fund】: 国家教育部归国留学人员基金资助项目
【CateGory Index】: O644
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 3 Hits
1 HU Wu-hong,SHEN Wei (Department of Chemistry,Fuling Normal College,Chongqing 408003,China);Theoretical study on reaction between COS with O_2 by density functional theory[J];Journal of Molecular Science;2005-04
2 FANG Lei1,ZHANG Yong-chun1,ZHOU Jin-xia1,DING Wei2(1.State Key Laboratory of Fine Chemical,Dilian University of Technology,Dalian 116012,China 2.Academy of Dilian University of Technology,Liaohe Peroleum Exploration Bureau 124010,China);Development of the Research in Removal of Low Concentration of COS from Industrial Exhaust Gas[J];Guangzhou Chemistry;2008-01
3 HU Wu-hong ,SHEN Wei(Department of Chemistry ,Fuling Normal College,Fuling 408003,China);Theoretical study on reaction between COS and O(~3P)[J];Journal of Xinyang Teachers College(Natural Science Edition);2005-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHNG Fan-gang (School of Environment and Resources, Renmin University of China,Beijing 100872,China);Qualitative and quantitative study on qrganic pollutants in the air of Shijingshan Gucheng district in Beijing[J];Journal of Anhui University(Natural Sciences);2002-02
2 KANG Shi-chang~(1,2),CONG Zhi-yuan~(1)(1.Institute of Tibetan Plateau Research,Chinese Academy of Sciences,Beijing,100085,China;2.Key Laboratory of Cryosphere and Environment,CAREERI,CAS,Lanzhou Gansu 730000,China);Progress in Study on Precipitation and Aerosol Chemistry in the Tibetan Plateau[J];Journal of Glaciology and Geocryology;2006-03
3 WANG Xuesong LI Jinlong (State Key Joint Laboratory of Environmental Simulation and Pollution Control,College of Environmental Sciences, Peking University,Beijing,100871);A Numerical Simulation Study of PM10 Pollution in Beijing during Summer Time[J];Acta Scicentiarum Naturalum Universitis Pekinesis;2003-03
4 ZHANG Zhanyi 1),3) LI Fengguo 2) YANG Guanling 2) LI Yifang 2) ZENG Fanjin 1) ZENG Limin 3) ( 1) Guangzhou Research Institute of Environmental Protection,Guangzhou,510620; 2) School of Physics and Telecom Engineering,South China Normal University,Guangzhou,510631; 3) College of Environmental Sciences,Peking University,Beijing,100871);Development of Analyzer for Atmospheric Particulate Matter Concentration and Its Performance Test[J];Acta Scientiarum Naturalium Universitatis Pekinensis;2006-06
5 DONG Huabin ZENG Limin 1)(State Key Joint Laboratory of Environmental Simulation and Pollution Control,and College of Environmental Sciences and Engineering,Peking University,Beijing,100871;An On-Line Method of Measuring Gaseous Ammonia and Ammonium in Aerosol in Atmosphere[J];Acta Scientiarum Naturalium Universitatis Pekinensis;2007-06
6 ZHOU Wei, WANG Xuesong, ZHANG Yuanhang, SU Hang, LU Keding College of Environmental Sciences and Engineering, Peking University, Beijing 100871;;Current Status of Nitrogen Oxides Related Pollution in China and Integrated Control Strategy[J];Acta Scientiarum Naturalium Universitatis Pekinensis;2008-02
7 CUI Mingming,WANG Xuesong,SU Hang,ZHANG Yuanhang College of Environmental Sciences and Engineering,Peking University,Beijing 100871;Chemical Characters and Sources Identification of PM_(10) in Guangzhou Area[J];Acta Scientiarum Naturalium Universitatis Pekinensis;2008-03
8 LLU Jing~1,ZHANG Jian-qiang~2,WU Xiang-yao~1,ZHANG Yu-yu~11.College of Materials and Chemical Engineering,Chengdu University of Technology,Chengdu 610059,China;2.College of Environmentology and Engineering,Southwest Jiaotong University,Chengdu 610031,China;Element components and sources analysis of atmospheric aerosols in the Shilidian area of Chengdu,China[J];Journal of Chengdu University of Technology(Science & Technology Edition);2006-01
9 ZHAO Guojun~1 BAO Qinghua~2 DONG Chenyang~3(1.Changchun entironmental inspect center,Changchun 130022;2.Jingyue entironmental inspect production brigade,Changchun 130011;3.Changchun entironmental protection office,Changchun 130021);Research on the Distributing Characteristic and Diversification Disciplinarian of Air Contaminations in Changchun City[J];Journal of Changchun Institute of Optics and Fine Mechanics;2005-03
10 QIN Baoping,XIE Hui,HAN Jing(Tianjin Environmental Monitoring Centre,Tianjin 300191,China);Study on the Ratio of Air Pollutant PM_(10) to TSP in Tianjin[J];Urban Environment & Urban Ecology;2002-06
China Proceedings of conference Full-text Database 3 Hits
1 Feng Hongfang Sui Ping Meteorological Institute of Fujian,Fuzhou 350001 Qiu Lixia Shaowu Meteorological Bureau,Fujian Province,Shaowu 354000;TEMPORAL AND SPATIAL DISTRIBUTIONS AND INFLUENCING FACTOR ANALYSIS OF AIR POLLUTANT CONCENTRATIONS IN FUZHOD CITY[A];[C];2005
2 Zhang Renojian~1 Fu Cong-bin~1 Cao Jun-ji~2 Wu Jian~(1,3) 1 Key Laboratory of Regional Climate-Environment Research for Temperate East Asia(REC-TEA),Institute of Atmospheric Physics,Chinese Academy of Sciences,Beijing 100029,China 2 Institute of Earth Environment,Chinese Academy of Sciences,Xi'an 710054,China 3 Department of Atmospheric Science,Yunnan University,Kunming 650091,China;Importance of Aerosol in Global Climate Change,Environment and Human Health[A];[C];2007
3 PU Weiwei,ZHANG Xiaoling,XU Jing,ZHAO Xiujuan,XU Xiaofeng,DONG Fan (The institute of urban meteorology, Center for Atmosphere Watch and Analysis of Beijing Meteorology Bureau ,CMA, Beijing, 100089);Analysis on characters and factors of acid rain in Beijing[A];[C];2009
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Zhang Qing-lin and Guo Han-xian (Research Institute of Coal Chemical Engineering, Taiyuan University of Technology);THE CHARACTERISTIC AND MECHANISM OF DEACTIVATION OF CARBONYL SULFIDE HYDROLYSIS CATALYST[J];Chinese Journal of Catalysis;1988-02
2 LIANG Meisheng 1,2*, LI Chunhu 1, GUO Hanxian 1, XIE Kechang 1 (1 State Key Laboratory of C1 Chemistry and Technology, Research Institute for Chemical Engineering of Coal; 2 College of Architecture and Environmental Engineering, Taiyuan University;Study on Reaction Kinetics of COS Hydrolysis at Lower Temperature[J];Chinese Journal of Catalysis;2002-04
3 LIU Shouxin 1,2 , SUN Chenglin 1* , ZHANG Shirun 2 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Northeast Forestry University, Harbin 150040, Heilongjiang, China);Photocatalytic Regeneration of Coal-Based Activated Carbon[J];Chinese Journal of Catalysis;2003-05
4 Liu Shouxin; Wang Yan(NorthCast Forestry University. Harbin 150040. P. R. China); Zheng Wenchao(Zoological Garden of Harbin);Progress in Activated Carbon Regeneration[J];Journal of Northeast Forestry University;2001-03
5 SUN Fu-nan,FENG Qing-xiang ,WU Jiang-hong (Guangming Research & Design Institute of Chemical Industry,Dalian 116031,China);The Production of High Purity Carbonyl Oxysulfide[J];Low Temperature and Specialty Gases;2004-03
6 XIAO Zhongbin1, ZHANG Yiqun1, MA Jianxin2, ZHOU Wei2, WU Minzhong2(1. Institute of Industrial catalysis, ECUST, Shanghai 200237, China;2. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 200092, China);Hydrolysis of Carbonyl Sulfide over Sulfidized Rare Earth Oxides[J];Journal of Fudan University;2003-03
7 ZHANG Yiqun1 , XIAO Zhongbin1 , MA Jianxin2 , ZHOU Wei2 , WU Minzhong2(1. Institute of Industrial Catalysis, Eeast China University of Science and Technology, Shanghai 200237, China;2. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 200092, China);Effect of O_2 and SO_2 on Hydrolysis of Carbonyl Sulfide over Rare Earth Oxysulfides[J];Journal of Fudan University;2003-03
8 Cheng Qing, Cao Changjun, Yao Xiaohong (Central Laboratory of Ethylene Plant, PetroChina Goup Dushanzi Petrochemicals Company, Dushanzi, 833600);Determination of trace carbonyl sulfur in propylene by gas chromatography with pulsed flame photometric detector.[J];Analytical Instrumentation;2006-02
9 PAN Xui mei,MA Ji cheng,FU Qiang,CHENG Chang,WANG Rong shun (Institute of Functional Material Chemistry,Faculty of Chemistry, Northeast Normal University,Changchun 130024,China);The DEF study of reaction of ·C_2H_3+O_2→HC·O+H_2CO[J];Journal Fo Molecular Science;2002-01
10 SUN Yang,WEI ZhiGang,HUANG XuRi,LI ZeSheng,SUN JiazhongInstitute of Theoretical Chemistry,Jilin University,Changchun 130023,China);Theoretical study on reaction mechanism of the vinyl radical with nitrogen dioxde[J];Journal of Molecular Science;2003-02
【Secondary References】
Chinese Journal Full-text Database 4 Hits
1 SUN Guang-ling, GENG Cai-yun, LI Ji-lai, HUANG Xu-ri, SUN Chia-chung ( Shengli Engineering & Consulting Co. Ltd, Dongying 257026,China; Institute of Theoretical Chemistry, State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023,China);A density functional theoretical study on the potential energy surface of the ethene hydrogenation catalyzed by metal Ir_4 cluster[J];Journal of Molecular Science;2006-03
2 WANG Yingjun,LIU Jinxiang,JIN Lili (Department of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,Heilongjiang,China);Advances in alkanes isomerization over tungsten based catalysts[J];Industrial Catalysis;2007-02
3 HE Ji-ling1,XU Qing-rong2,LI Xian-cai2(1.Jiangxi Torch High & New Technology Development Co.Ltd.,Nanchang 330029,Jiangxi,China;2.Department of Chemistry,Nanchang University,Nanchang 330031,Jiangxi,China);Research Progress of Ultra-fine WC Preparation[J];China Tungsten Industry;2008-06
4 SHAO Gang-qin,SUN Peng,ZHANG Qing-jie,ZHOU Fu-rong,WANG Tian-guo,XIONG Zhen(State Key Laboratory of Advanced Technology for Materials Synthesis & Processing,Wuhan University of Technology,Wuhan 430070,China);Hydroisomerization Properties of Platinum-like Tungsten Carbide Catalyst[J];Journal of Wuhan University of Technology;2009-19
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved