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《CHINESE JOURNAL OF LUMINESCENCE》 1995-02
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SYNTHESIS,SPECTRA AND Eu(Ⅲ)SITES OF Eu_2(DBM)_6 4, 4'-BIPY

Wang Mingzhao;Jin Linpei(Department of Chemistry, Beijing Normal Universiy,Beijing 100875)Lu Shaozhe;Zhang Jiahua(Changchun Institute of Physics,Chinese Academy of Sciences,Changchun 130021)  
The complex, Eu2 (DBM )64,4'-BIPY,is synthesized and characterized with elemental analysis,IR spectra and Raman spectra.High-resolved laser-excited excitation and luminescence spectra under 77K show that there are two Eu(Ⅲ) sites in the complex,and the energy difference between 5D0 levels of two Eu (Ⅲ) sites is 15 cm-1. Neither one of the two kinds of Eu(Ⅲ)ions is in symmetric center.The components of 5D0→7F0.1.2transitions indicate the local symmetries of both Eu(Ⅲ) sites are C1orC2 or C3.Luminescent lifetimes of the two kinds of Eu(Ⅲ)ions are 0.37 ms and 0. 32 ms respectively.
【Fund】: 国家自然科学基金 中国科学院长春物理研究所激发态物理研究开放实验室资助
【CateGory Index】: O433.51
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【Co-references】
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