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《CHINESE JOURNAL OF LUMINESCENCE》 1997-02
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PHOTOLUMINESCENCE AND APPLICATION OF CaS∶Cu +, Eu 2+

Lian Shixun Mao Xianghui Wu Zhenguo Li Chenzhi Zhen Yao (Department of Chemistry, Hunan Normal University, Changsha 410006)  
The fluorescence of Cu + and Eu 2+ coactivated CaS is reported. The emission bands of Cu +and Eu 2+ peaking at 430 nm and 630 nm were originated from Cu + transition of Cu , Ca V S 2+ centers and 5d-4f transition of Eu 2+ , respectively. The dependence of luminescence properties of Cu +nd Eu 2+ on their concentration was investigatad. The emission of Eu 2+ is sensitized by Cu + and the peak wavelength and intensity of Cu + emission band are affected by Eu 2+ . The experimental results indicate that there exists effective energy transfer from Cu + to Eu 2+ in CaS host. CaS∶Cu + and CaS∶Eu 2+ are good red light transition agent and blue light trasition agent for farm film, respectively. The absorption spectrum of chlorophyll photosynthesis can be imitated by light transition film for farm using CaS∶Cu +, Eu 2+ phosphor as additive, Which can make the crops growth in the environment of function spectrum of the best growth of plants, and promote its growth or increase yield.
【Fund】: 湖南省计委资助
【CateGory Index】: TN383.2:S3
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