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Kinetics study of the coomparison on the discoloration of dyes in aqueous solutions induced by photolysis of Fe(Ⅲ)-carboxylate complexes

Luo Fan;Wu Feng;Deng Nansheng;Xiao Mei(Department of Environmental Science,Wuhan University Wuhan 430072)  
The discoloration of dye C. I. reactive red 2 can be accelerated in aqueous solutions containing Fe (Ⅱ )-carboxylate complexes )citrate, oxalate, succinate and tartarate) under near-UV light irradiation 313 m,250W). The discoloration of dye solutions in concentration range 10 mg/L-50 mg/L is pseudo-first order reaction,and the discoloration rate decrease with increasing the initial dye concentration. Optimum pH for photochemical discoloration of dye solutions by Fe(Ⅲ)-citrate,succinate and tartarate respectively is 2.0-3. 0,while 4. 0 by Fe (Ⅱ)-oxalato complex. The Fe3+/Carboxylate ratio have effects on the,discoloration efficiency.
【Fund】: 湖北省自然科学基金
【CateGory Index】: O614.811
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