Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Liaoning University of Petroleum & Chemical Technology》 2006-02
Add to Favorite Get Latest Update

Catalytic Synthesis of Tetradecylbenzene With Supported HF/USY Catalyst

LIU Chuan-bin,WANG Yue-mei,SHEN Jian~* (School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology, Fushun Liaoning 113001,P.R.China)  
Tetradecylbenzene was prepared by the alkylation of benzene with tetradecene over supported hydrofluoric acid on USY.[CM(53*3]The catalytic performances of the catalysts were investigated by alkylation reaction of benzene and tetradecene in a liquid fixed micro-reactor.The influences of reaction temperature,calcination temperature,space velocity and the composition of the catalysts on the catalytic performances were studied.Then the catalyst stability performance was also studied.The results show that the conversion of tetradecene is 98.54% and selectivity of 2-tetradecylbenzene is 52.68% under the conditions of 6.0% mass fraction of fluorine,300 ℃ calcinations temperature,140 ℃ reaction temperature,3.0 h~(-1) space velocity(WHSV),and 10∶1 of mole ratio of benzene and tetradecene.HF/USY catalysts have highly activity and stability.
【CateGory Index】: O625.1;O643.36
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 3 Hits
1 LI Li1,2,GAO Wen-yi1,DAI Xi-hai2,REN Li-guo1﹡,LU Zhen-hua(1.School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China;2.Detergent Chemical Factory of Fushun Petrochemical Company CNPC,Fushun Liaoning 113001,P.R.China)Received 11 September 2006;revised 15 December 2006;accepted 25 December 2006;Liquid Phase Alkylation of Benzene With 1-Dodecene Catalyzed by Methanesulfonic Acid[J];Journal of Liaoning University of Petroleum & Chemical Technology;2007-01
2 WEN Qinwu,SHEN Jian,YANG Lina,LIU Chuanbin (Department of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning China);Synthesis of dodecylbenzene over supported HF/USY catalyst[J];Industrial Catalysis;2007-07
3 Wu Bing~1 Shen Jian~1 Li Huipeng~1 Feng Jian~2 1. Liaoning University of Petroleum and Chemical Technology, Fushun 113001,Liaoning, China; 2. Delayed Coker Plant of Liaohe Petrochemical Corporation,China Petroleum, Panjin 124022, Liaoning, China;SYNTHESIS OF p-tert-BUTYLPHENOL OVER SUPPORTED HYDROGEN FLUORIDE/USY CATALYST[J];Speciality Petrochemicals;2008-02
【Citations】
Chinese Journal Full-text Database 7 Hits
1 Li Ji Liang (LAB Plant of Jinling Petrochemical Corp.,Nanjing 210046,China);The Recent Application Status of Linear Alkylbenzene Derivatives[J];CHINA SURFACTANT DETERGENT & COSMETICS;2000-03
2 Zhao Yonggang, Jin Yingjie, Ren Jie * (Department of Petrochemical Technology ,Fushun Petroleum Institute ,Liaoning Fushun 113001, China);Study on Reaction Kinetics of Linear Alkylbenzene Formation over Solid Acid Catalysts[J];JOURNAL OF FUSHUN PETROLEUM INSTITUTE;2000-03
3 MA Jun, WANG Hai-yan, WEI Min, DAI Dan, MIAO Xing-dong (School of Petrochemical Technology, Liaoning University of Petroleum & Chemical Technology, Fushun Liaoning 113001,P.R.China) Received 13 January 2004; revised 18 April 2004; accepted 2 June 2004;Etherification and Modifiction on β Zeolite Catalyst[J];;2004-03
4 Liu Xianyi (Catalyst Complex of Qilu Petrochemical Corp., Zibo, Shandong 255300);Discussion on Factors Affecting the Quality of USY Zeolites[J];Qilu Petrochemical Technology;2001-03
5 Wang Yuemei,Shen jian,Yuan Xingdong,et al.(Petrochemical Institute,Liaoning Petrochemical University);Synthesis of Hexadecylbenzene Oversupported HF on USY Catalyst[J];Chemical Engineering of Oil and Gas;2005-01
6 Wang Xing,Xu Longya and Wang Qingxia(Dalian Institute of Chemical Physics,Academia Sinica,Dalian 116023)Gao Yuhua,Gao Shen and Mu Min(Institute of Fushun Petrochemical Corporation,Fushun 113006);Benzene Alkylation with Long Chain Olefine to Produce LAB Ⅰ.Study of Fluorinated Ytype Zeolite /Superacid Catalysts[J];PETROCHEMICAL TECHNOLOGY;1998-04
7 WANG Er-qiang, ZHANG Jin-chang, LI Cheng-yue (Key Lab of the Department of Basic Education on Science and Technology of Controllable Chemical Reactions, Beijing University of Chemical Technology, Beijing 100029, China);Research progress in alkylation reaction of benzene with long chain alkenes[J];Modern Chemical Industry;2002-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 XIE Fu-sheng ZHANG Jin-chang LI Cheng-yue(The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry ofEducation, Beijing University of Chemical Technology, Beijing 100029, China);Investigation of reaction conditions in synthesis of linear alkylbenzene using supported heteropoly acid in a fixed-bed reactor[J];Journal of Beijing University of Chemical Technology;2005-02
2 LI Juan~1 YAN Shi-cheng~2 LI Jian-wei~1 CHEN Biao-hua~1 DENG Wei~1(1.State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Jilin Vocational College of Industry and Technology,Jilin 132000,China);Dodecylbenzene synthesis by the alkylation of benzene with 1-dodecene over mesoporous zeolites[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2006-06
3 CHENG Yu~1,SHEN Jian~1,BA Heng-fei~2,KONG De-lin~2(1.School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,China;2.Petroleum & Chemical Technology Company of Fushun,Fushun 113001,China);Synthesis of hexadecylbenzene over supported HF on USY catalyst[J];China Surfactant Detergent & Cosmetics;2006-05
4 WEN Langyou 1, SHEN Shikong 1, MIN Enze 2 (1 School of Chemical Engineering, University of Petroleum (Beijing), Beijing 102200, China; 2 Research Institute of Petrochemical Processing, SINOPEC, Beijing 100083, China);Alkylation of Benzene with 1-Dodecene Catalyzed by Heteropoly Acids[J];Chinese Journal of Catalysis;2000-06
5 TIAN Ling,LI Jianwei,LI Yingxia,CHEN Biaohua(State Key Laboratory of Chemical Resources Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Synthesis of Dodecylbenzene with Benzene and 1-Dodecene over MCM-22 Zeolite Modified with Phosphorus[J];Chinese Journal of Catalysis;2008-09
6 WANG Li,WANG Hai-yan,CHEN Jin-peng(Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China);Macrokinetics Studying on Catalyic Synthesis of TAME by β Zeolite[J];Journal of Liaoning University of Petroleum & Chemical Technology;2006-01
7 LI Li1,2,GAO Wen-yi1,DAI Xi-hai2,REN Li-guo1﹡,LU Zhen-hua(1.School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China;2.Detergent Chemical Factory of Fushun Petrochemical Company CNPC,Fushun Liaoning 113001,P.R.China)Received 11 September 2006;revised 15 December 2006;accepted 25 December 2006;Liquid Phase Alkylation of Benzene With 1-Dodecene Catalyzed by Methanesulfonic Acid[J];Journal of Liaoning University of Petroleum & Chemical Technology;2007-01
8 LIAO Ke-jian,ZHANG Ling,CONG Yu-feng,SUN Feng-jiao,YU Hong-bo(School of Petrochemical Engineering,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China);Preparation of Horniness Oxidized Wax by Catalytic Oxidation[J];Journal of Liaoning University of Petroleum & Chemical Technology;2008-04
9 XU Zhao-yu (Anhui Research Institute of Chemical Industry,Hefei 230041,China);Development and Application of Molecular Sieve[J];Technology & Development of Chemical Industry;2007-07
10 WEN Qinwu,SHEN Jian,YANG Lina,LIU Chuanbin (Department of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning China);Synthesis of dodecylbenzene over supported HF/USY catalyst[J];Industrial Catalysis;2007-07
【Co-references】
Chinese Journal Full-text Database 9 Hits
1 Li Ji Liang (LAB Plant of Jinling Petrochemical Corp.,Nanjing 210046,China);The Recent Application Status of Linear Alkylbenzene Derivatives[J];CHINA SURFACTANT DETERGENT & COSMETICS;2000-03
2 MA Jun, WANG Hai-yan, WEI Min, DAI Dan, MIAO Xing-dong (School of Petrochemical Technology, Liaoning University of Petroleum & Chemical Technology, Fushun Liaoning 113001,P.R.China) Received 13 January 2004; revised 18 April 2004; accepted 2 June 2004;Etherification and Modifiction on β Zeolite Catalyst[J];;2004-03
3 Wang Xianyang (Department of Chemistry, Anhui Medical University, Hefei 230032);Synthesis of Linear Alkylbenzene Catalyzed by Ionic Liquid[J];Advances in Fine Fetrochemicals;2005-02
4 ZHOU Zhi-feng(Technical and Economic Information Center of Petro-Chemical Industry of Liaoning Province,Shenyang, 110004);Advances in Research on Alkylation of Benzene with 1-Dodecene[J];Liaoning Chemical Industry;2005-06
5 Wang Yuemei,Shen jian,Yuan Xingdong,et al.(Petrochemical Institute,Liaoning Petrochemical University);Synthesis of Hexadecylbenzene Oversupported HF on USY Catalyst[J];Chemical Engineering of Oil and Gas;2005-01
6 ZHANG Jin-chang,LI Cheng-yue,ZHU Zuo-gang,CHEN Biao-hua,LI Ying-xia (The Key Laboratory of Science and Technology of Controllable Chemical Reactions,Ministry of Education, Beijing University of Chemical Technology,Beijing 100029,China);Study of Environmental Friendly Solid Acid Catalysts for Synthesizing Linear Alkybenzene Ⅱ.Process Conditions of Synthesizing Linear Alkylbenzene by Solid Acid Catalyst[J];Petrochemical Technology;2002-12
7 Wang Xing,Xu Longya and Wang Qingxia(Dalian Institute of Chemical Physics,Academia Sinica,Dalian 116023)Gao Yuhua,Gao Shen and Mu Min(Institute of Fushun Petrochemical Corporation,Fushun 113006);Benzene Alkylation with Long Chain Olefine to Produce LAB Ⅰ.Study of Fluorinated Ytype Zeolite /Superacid Catalysts[J];PETROCHEMICAL TECHNOLOGY;1998-04
8 GAO Wen-yi,REN Li-guo(School of Petrochemical Technology, Liaoning University of Petroleum & Chemical Technology, Fushun Liaoning 113001, China);ZrPAl Solid Acid Catalyst on Benzene Wiuh Long-Chain Alkene[J];Journal of Petrochemical Universities;2004-02
9 WANG Er-qiang, ZHANG Jin-chang, LI Cheng-yue (Key Lab of the Department of Basic Education on Science and Technology of Controllable Chemical Reactions, Beijing University of Chemical Technology, Beijing 100029, China);Research progress in alkylation reaction of benzene with long chain alkenes[J];Modern Chemical Industry;2002-02
【Secondary References】
Chinese Journal Full-text Database 6 Hits
1 REN Liguo ZHANG Xiaoli GAO Wenyi (School of Chemical & Material Science,Liaoning Shihua University,Fushun 113001,Liaoning,China);Synthesis of biodiesel via transesterification over silica-supported methanesulfonic acid[J];Industrial Catalysis;2009-10
2 SONG Wei,XU Xue-li,SHI Heng-xin (Nanyang Institute of Technology The department of biology and chemistry,Nanyang 473000,China);Synthesis of 2-Dodecylbenzene with Supported Heteropoly Acid on the Surface of Silicon Dioxide as Catalyst[J];Fine Chemical Intermediates;2008-03
3 WANG Chao~(1,3),SUN Xian-li~2,SHEN Jian~1,YANG Yan-ming~4(1.School of Petrochemical Engineering,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning Province,China;2.Petrochemical General Plant,Liaohe Petroleum Exploration Bureau,Panjin 124022,Liaoning Province,China;3.Bohai Sea Drilling Project Company,Renqiu 062552,Hebei Province,China;4.Petrochina Huabei Oilfield Company,Renqiu 062552,Hebei Province,China);Synthesis of Hexadecylbenzene over Supported Phosphoric Acid on SBA-15 Catalyst[J];Chemical Industry and Engineering;2009-03
4 HOU Qi-jun (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China);Greening of Surfactant Industry[J];Fine and Specialty Chemicals;2008-19
5 Qian Guangwei,Wu Qian,Xu Denghua,Yu Zhaoxiang(Department of Chemistry,Tongji University,Shanghai 200092,China);Effect of pore enlarged of USY catalysts in hydrocracking of low-temperature coal tar[J];Science & Technology in Chemical Industry;2013-03
6 YANG Guang1,WANG Lei-bo2 (1.Liaoning Shihua university,Liaoning Fushun 113001,China;2. Fushun petrochemical company,Liaoning Fushun 113001,China);Study on Alkylation by Carbon-based p-toluene Sulfonic Acid Catalyst[J];Contemporary Chemical Industry;2010-01
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Li Ji Liang (LAB Plant of Jinling Petrochemical Corp.,Nanjing 210046,China);The Recent Application Status of Linear Alkylbenzene Derivatives[J];CHINA SURFACTANT DETERGENT & COSMETICS;2000-03
2 CUI Bao-chen,LIU Shu-zhi,DONG Qun( College of Chemistry and Chemical Engineering,Daqing Petroleum Institute, Daq ing, Heilongjiang 163318, China );Preparation of solid super-strong acid zeolite and catalytic properties of ethe rification[J];Journal of Daqing Petroleum Institute;2003-03
3 Deng Wei, Jin Yingjie, Ren Jie (Department of Petrochemical Technology, Fushun Petroleum Institute, Liaoning Fushun 113001, China);Alkylation of Benzene with Long Chain Olefins over PW/MCM-41[J];JOURNAL OF FUSHUN PETROLEUM INSTITUTE;2000-01
4 Liang Wugeng. Wang Yao. Yu Zhiqing. Jin Yong and Wang Zhanwen(Department of Chemical Engineering,Tsinghua University Beijimg 100084);SYNTHESIS OF LINEAR ALKYLBENZENE IN LIQUID-SOLID CIRCULATING FLUIDIZED BED REACTOR[J];Journal of Chemical Industry and Engineering(China);1995-01
5 Wang Haiyan,Qi Yutai,Zhou Ding Department of Environmental Engineering and Science,Harbin Institute of Technology (Harbin,Heilongjiang 150001);PRODUCTION OF CLEAN GASOLINE BY LIGHT FCC GASOLINE ETHERFICATION[J];Petroleum Refinery Engineering;2000-10
6 Jin Yingjie Ren Jie Yuan Xingdong Shen Jian (Department of Petrochemical Technology Fushun Petroleum Institute Fushun) Zhou Jinglai (Institute of Coal Chemistry Chinese Academy of Sciences Taiyuan);ALKYLATION OF BENZENE WITH LONG CHAIN OLEFINE OVER SUPPORTED MESOPOROUS MOLECULAR SIEVES[J];JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY;1999-06
7 Ren Jie(Department of Petrochemical Technology, Fushun Petroleum Institute, Fushun 113001)Chen Shaozhou(Research Center of Petroleum Processing, East China University of Chemical Technology, Shanghai 200237);Study on the Regeneration Ability of Zeolite Catalyst for the Alkylation of Benzene with Long Chain Alkene[J];Petrochemical Technology;1993-08
8 Reaction Process CUI Zhe,HAN Ming-han,CHEN Wei and JIN Yong (Department of Chemical Engineering,Qinghua University,Beijing 100084);Synthesis of Linear Alkylbenzene Using TH-06 Catalyst[J];PETROCHEMICAL TECHNOLOGY;1999-10
9 LI Li,PAN Hui-fang,LI Wen-bing (CNPC Key Lab of Catalysis,University of Petroleum,Beijing 102200,China);Synthesis of β Zeolite and Its Application in Cracking Catalyst[J];Petrochemical Technology;2002-03
10 Wang Xing,Xu Longya and Wang Qingxia(Dalian Institute of Chemical Physics,Academia Sinica,Dalian 116023)Gao Yuhua,Gao Shen and Mu Min(Institute of Fushun Petrochemical Corporation,Fushun 113006);Benzene Alkylation with Long Chain Olefine to Produce LAB Ⅰ.Study of Fluorinated Ytype Zeolite /Superacid Catalysts[J];PETROCHEMICAL TECHNOLOGY;1998-04
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved