Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Minjiang University》 2008-02
Add to Favorite Get Latest Update

Determination of hydrolysis rate constant for carbaryl by electrochemical technique

CHEN Yi-ting1,CHEN Jing-hua2,ZHENG Huang-huang1(1.Department of Chemistry and Chemical Engineering,Minjiang University,Fuzhou,Fujian 350108,China;2.Department of Pharmaceutical Analysis,Fujian Medical University,Fuzhou,Fujian 350004,China)  
The hydrolysis behavior of carbaryl was investigated by cyclic voltammetry(CV) and different pulse voltammetry(DPV) at a glassy carbon electrode(GCE),and the hydrolysis rate constants at different pH value and temperature were determined.The experiment indicates that the hydrolysis of carbaryl is one order reaction,and the carbaryl also could hydrolyze in acidic medium,but the speed of the hydrolysis was lower than that in alkaline medium.In addition,the temperature 9 obviously affecs the hydrolysis rate in acidic and alkaline medium.
【Fund】: 国家863计划(2006AA02Z4Z1);; 福建省教育厅科技项目(JB07168);; 福建省教育厅科研基金资助项目(2005K051);; 福建省卫生厅青年科研基金资助项目(2005123)
【CateGory Index】: O657.1
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 6 Hits
1 HE Yu,HUANG Chun-mao,TONG Ping,ZHANG Lan (Key Laboratory of Analysis and Detection Technology for Food Safety,Ministry of Education,The Sport Science Research Center,Fuzhou University,Fuzhou 350002,China);The Study of the Voltammetric Behaviour of 7-methylguanosine on Glassy Carbon Electrode[J];Analysis and Testing Technology and Instruments;2007-01
2 Du Yushan~(1,2),Chen Guanhua~(1),Hou Fangfei~(1,2),Cao Jia~(1,2) (College of Life Science~1,College of Food Science~2,Agricultural University of Hebei,Baoding 071001);Fluorescent Spectrophotometric Determination of Hydrolytic Residue Carbaryl Sensitized by Cetyltrimethylammonium Bromide[J];Chinese Journal of Analytical Chemistry;2006-04
3 ZHANG Xiao-ming ZHOU Zhi-qiang XU Yan-jun SUN Ying LI Zi-xiang(College of Science,China Agricultural University,Beijing,100094,China);HYDROLYSIS AND THE INFLUENCING FACTORS OF CARBARYL IN WATER[J];Environmental Chemistry;2006-05
4 Wang Jianhua,Jiao Kui*,Lin Liming,Xie Zhihai,Cheng Gang(Shandong Import & Export Commodity Inspection Bureau,Qingdao 266002);Determination of Four Carbamate Residues in Rice by RP_HPLC with Amperometric Detection[J];JOURNAL OF INSTRUMENTAL ANALYSIS;1998-03
5 Liang Qi, Yan Qingchang(Guangdong Provincial Institute for Drug Control, Guangzhou 510180);Determination of Methylcarbamate Pesticides Residue in Chinese Traditional Medicine Radix Astragali by Capillary Gas Chromatography[J];JOURNAL OF INSTRUMENTAL ANALYSIS;1999-02
6 WANG Yu-tian~1,WANG Zhong-dong~(1,2) (1.Yanshan University,Qinhuangdao 066004,China;2.Daqing Petroleum Institute,Qinhuangdao 066004,China);Study on Fluorescence Spectrometer for Monitoring Pesticide Residues in Vegetables[J];Journal of Applied Optics;2005-05
Chinese Journal Full-text Database 10 Hits
1 WU Xue-ping et al (Henan Institute of Science and Technology,Xinxiang,Henan 453003 );Sensitivity Mensuration of Wheat Seed to Pquincloracp[J];Journal of Anhui Agricultural Sciences;2006-12
2 WU Xue-ping et al (Henan Institute of Science and Technology,Xinxiang,Henan 453003);Study on the Effect of Two Kinds of Penoxulam Herbicides on Wheat Seed Biologic Activity[J];Journal of Anhui Agricultural Sciences;2006-17
3 WU Xue-ping et al (Henan Institute of Science and Technology,Xinxiang,Henan 453003);Sensitivity Measure of Wheat Seed Root to Tribenuron-methyl[J];Journal of Anhui Agricultural Sciences;2006-18
4 GUO Zhi-qiang et al(Analysis and Test Center of CATAS,Haikou,Hainan 571101);The Application of Organic Synthesize in the Pesticide[J];Journal of Anhui Agricultural Sciences;2007-32
5 ZHANG Ying-peng et al(Institute of Organic and Medicinal Chemistry,College of Petrochemical Engineering,Lanzhou University of Technology,Lanzhou,Gansu 730050);Study on Preparation of Three Pesticide Formulations from Extract of Tagetes Root and Their Activities[J];Journal of Anhui Agricultural Sciences;2008-15
6 YAN Shi et al(School of Environmental and Biological Engineering,Shenyang Institute of Chemical Industry,Shenyang,Liaoning 110142);Study on the Principle of the Detection Rate of the Different Types of the Pesticide Residues in Vegetable[J];Journal of Anhui Agricultural Sciences;2008-35
7 YANG Xiu-juan et al(Environment and Plant Protection College,Hainan University,Danzhou,Hainan 571737);Study on Antibacterial Activity of Crude Extractions of Mango Nucleolus on Several Kinds of Plant Pathogen[J];Journal of Anhui Agricultural Sciences;2009-06
8 WU Xin-an,HUA Ri-mao,YUE Yong-de,WU Xiang-wei,YANG Xiao-fan (Department of Plant Protection,Anhui Agricultural University,Hefei 230036);Studies on the Antifungal Activity of Seven Herbs on Plant Pathogen[J];Journal of Anhui Agricultural University;2002-04
9 ZHANG Xiang-zhu~1,WU Ming-shu~2(1.Anyang University,Anyang 455000,China;2.Anyang County Environmental Protection Bureau,Anyang 455000,China);On Modern Technology of Agricultural Chemicals and Sustainable Development of Ecological Environment[J];Journal of Anyang Teachers College;2004-05
10 BU Wei~1(1.Taizhou City Environmental Monitoring Central Station,Jiangsu 225300,China);Water Quality-Solid Phase Extract-HPLC Determination of Disinfectant Multi-fungi in Insecticide[J];Environmental Science and Management;2006-08
China Proceedings of conference Full-text Database 4 Hits
1 Zhang Xiaoming,Xu Yanjun,Mao Chaoshu,Li Zixiang,Sun Ying (Department of Applied Chemistry,College of Science,China Agricultural University, Beijing 100094,China);Effect of pH on the Hydrolysis and Kinetics Of Carbaryl[A];[C];2005
2 Li Donghao,Zhang Xiao ming,Sun Ying,Liu hui (Department of Applied Chemistry,College of Science,China Agricultural University, Beijing 100094, China);The Comparison of the Analytical Methods for Carbamate Pesticide Residues[A];[C];2005
3 Liu Xinyan,Ouyang Xihui,Pan Canping (Department of Applied Chemistry,College of Science, China Agricultural University,Beijing 100094,China);Review on The Residue Analysis Methods for Bioregulators in Strawberry and Other Fruits[A];[C];2005
4 ZHOU Jing-gang,GUO Zheng-yuan,LIANG Jing,FENG Li-ping (Institute of Aro-Environmental Protection, Hunan Agricultural University, Changsha 410128,China);Residue analysis and degradation dynamics of carbaryl in pakchoi[A];[C];2007
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 WANG Yutian\ \ LIU Rui(Department of Instrument Science, Yanshan University, Qinhuangdao Hebei 066004, P.R.China);Study of Fiber-Optical Fluorescence Spectrometer for Monitoring Carbamate Pesticides[J];Journal of Transcluction Technology;2003-03
2 ZHANG Lan, YANG Juan, CHEN Jiang, CHEN Guo-nan (Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China);Differential Pulse Voltammetry Study on 1-Methylguanosine[J];Analysis and Testing Technology and Instruments;2004-02
3 Cheng Zhiliang, Yang Xiurong * (Laboratory of Electroanalytical Chemistry, National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Characterization of Multilayer Film Using Electrochemical Impedance Spectroscopy[J];Chinese Journal of Analytieal Chemistry;2001-01
4 Yang Yunfa (Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun 130022);Anodic Voltammetry of Dipyridamole at a Glassy Carbon Electrode[J];Chinese Journal of Analytieal Chemistry;2001-01
5 Song Junfeng *,Xue Jing,Guo Wei (Institute of Electroanalytical Chemistry, Northwest University, Xian 710069);Determinaiton of Benzaldehyde Based on Polarographic Catalytic Wave of Benzaldehyde Hydrozone as Derivative in the Presence of K_2S_2O_8[J];Chinese Journal of Analytieal Chemistry;2001-01
6 Wei Peihai, Chen Liren (Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000) Li Guanbin * (Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan 250100) [WT5HZ];Electrocatalytic Oxidation and Detection of Phenols at Stannic Oxide Modified Carbon Fiber Electrode[J];Chinese Journal of Analytieal Chemistry;2001-01
7 Liu Yongming, Li Guizhi  (College of Chemistry, Yantai University, Yantai 264005);Indirect Determination of Benzhexoli in Tablets by Inductively Coupled Plasma-Atomic Emission Spectroscopy[J];Chinese Journal of Analytieal Chemistry;2001-01
8 Zhang Jun,Tang Chunyang,Zheng Jianbin * (Institute of Electroanalytical Chemistry, Northwest University, Xi′an 710069);Application of Resilient Propagation Neural Network in Determination of Trace Chromium with Oscillographic Chronopotentiometry[J];Chinese Journal of Analytieal Chemistry;2001-01
9 in Tanning Material of Leather by Potential Titration with Catalytic End point Indication$$$$ Dong Xuezhi , Zhao Hailan, Ai Tianzhong, He Haihua, Wei Lingheng (Department of Chemistry, Henan University, Kaifeng 475001);Determination of Chromium Ⅲ in Tanning Material of Leather by Potential Titration with Catalytic End-point Indication[J];Chinese Journal of Analytieal Chemistry;2001-01
10 Wang Zhenhui 1 , Zhang Dai 1, Zhang Yan 2, Zhou Shuping 1 1(College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453002) 2(Pingdingshan Urban Construction and Enviornmental Protection School, Pingdings;Voltammetric Behavior of Dicynonum at Poly(4-aminopyridine) Film Modified Electrode and Its Determination by Adsorptive Stripping Voltammetry[J];Chinese Journal of Analytieal Chemistry;2001-01
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved