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《Journal of Minjiang University》 2008-02
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Determination of hydrolysis rate constant for carbaryl by electrochemical technique

CHEN Yi-ting1,CHEN Jing-hua2,ZHENG Huang-huang1(1.Department of Chemistry and Chemical Engineering,Minjiang University,Fuzhou,Fujian 350108,China;2.Department of Pharmaceutical Analysis,Fujian Medical University,Fuzhou,Fujian 350004,China)  
The hydrolysis behavior of carbaryl was investigated by cyclic voltammetry(CV) and different pulse voltammetry(DPV) at a glassy carbon electrode(GCE),and the hydrolysis rate constants at different pH value and temperature were determined.The experiment indicates that the hydrolysis of carbaryl is one order reaction,and the carbaryl also could hydrolyze in acidic medium,but the speed of the hydrolysis was lower than that in alkaline medium.In addition,the temperature 9 obviously affecs the hydrolysis rate in acidic and alkaline medium.
【Fund】: 国家863计划(2006AA02Z4Z1);; 福建省教育厅科技项目(JB07168);; 福建省教育厅科研基金资助项目(2005K051);; 福建省卫生厅青年科研基金资助项目(2005123)
【CateGory Index】: O657.1
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