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《Acta Materiae Compositae Sinica》 2014-05
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Effects of SiC_W on porous Al_2TiO_5-SiC_W composites by reaction sintering

LI Shuhai;CUI Hongzhi;ZHENG Wenlong;CUI Deyun;School of Materials Science and Engineering,Shandong University of Science and Technology;  
Porous Al2TiO5-SiCwcomposites were prepared by reaction sintering withγ-AlOOH,TiO2 and SiCwas raw materials.The effects of SiCwon phases,microstructures,porosity and compressive strength of Al2TiO5-SiCw composites were investigated.The results show that the main phases of the reaction products are Al2TiO5,Al6Si2O13,TiC and SiO2.SiCwreacts completely with TiO2 to form TiC and SiO2 because of the fast decomposition of slender SiCw.With the addition of SiCw,the microstructures of Al2TiO5 composites are significantly refined.The fine regular TiC grains and Al6Si2O13 grains which distribute between the grain boundaries of Al2TiO5 can impede the growth of Al2TiO5 grains and improve the compressive strength of the porous Al2TiO5 composites.Moreover,because SiCwchanges the packing form of the raw materials and increases the pore size,its porosity increases notably.In addition,some SiO2 existing among the crystalline grains makes the walls of pores denser and increases the compressive strength of Al2TiO5 composites,but the compressive strength will decrease when the content of SiCwis excessive for the appearance of more glass phase.
【Fund】: 国家自然科学基金(51072104 51272141);; 山东省“泰山学者”计划(ts20110828)
【CateGory Index】: TB332
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