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《ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS》 2000-01
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Study on Resonance Scattering Spectroscopy for the Photochemical Reaction of Silver(Ⅰ) and Benzoglycolic Acid

WANG Liuping 1 JIANG Zhiliang 2 1(Liuzhou Railway Transport school\ Liuzhou\ 545000) \ \+2(The Chllege of Chemistry and Life Science, Guangxi Noirmal University\ Guilin\ 541004)  
In the medium of 0.04 mol/L sulphuric acid and 0.01 mol/L benzoglycolic acid, silver(Ⅰ) was reduced photochemically to silver sol and benznglycolic acid was oxidized photo chemically to benzaldehrde. Thesilver sol exhibits strongly a resonance scattering peak at 525 nm. The intensity is proportional to silver concentration in the range of 0.1 and 4.0 μg/mL. This method has been applied to the detemination of silver in wastewater. The photochmical reaction has been investigated by resonance scattering spectroscopy, UV spectropho-tometry and oscillopolarography. The reaction mechanism and the phenomenon of scattering were discussed.
【Fund】: 广西教育厅资助项目
【CateGory Index】: O657.3
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