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《Analysis and Testing Technology and Instruments》 2005-02
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Spectral Properties of Cationic Surfactant-I~-_3 Association Particle System and Its Analytical Application

CHENG Yun-yan, LUO Yang-he, JIANG Zhi-liang (Department of Resource and Environmental Science, Guangxi Normal University, Guilin 541004, China)  
In 0.01 mol/L HCl medium, there is a max absorption peak at 350 nm for I~-_3. The association particle system of (CTMAB-I_3)_n is in violet-red color. It has a new absorption peak at 550 nm. The CTMAB concentration C_(CTMAB) in the range of 0.0~7.0×10~(-5) mol/L is linear to the A_(550 nm) value. Its regression equation is A_(550 nm)=0.989×10~4 C_(CTMAB)+0.0138,regression coefficient is 0.9995. The mole absorption coefficient is 1.06×10~4 L/(mol·cm). A new spectrophotometric method has been proposed for the determination of cationic surfactant. The resonance scattering spectra show that the CTMAB~+ and I~-_3 combine to CTMA-I_3 association molecule by means of attract forces. The association molecules automatically aggregate to (I_3-CTMA)_n association particles. So that, the particles exhibit a resonance scattering peaks at 580 nm, and the system is in violet\|red.
【Fund】: 广西自然科学基金资助项目(No.014403).
【CateGory Index】: O647.2
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