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《Chinese Journal of Analytical Chemistry》 1992-06
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Synthesis of Dibromocarboxylbenzenediazoaminoazobenzene and Its Color Reaction With Cadmium

Wang Lei, Sun Peipei, Shen Naikui (Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000)  
The synthesis of dibromocarboxylbenzenediazoaminoazobenzene, (DB-o-CDAA and DB-p-CDAA), and the condition of their color reaction with Cd(Ⅰ) are reported. The results show that the color reagents react with Cd(Ⅰ) to form stable orange-sed complexes (2:1) in the presence of Triton X-100 and at pH 10.2. The absorption maximum and molar absorptivity of the color reaction are found to be 520, 508nm and 2.21x10~5, 1.12×10~5L. mol~(-1). cm~(-1) for DB-o-CDAA and DB-p-CDAA, respectively. The structure of the complex was suggested. Beer's law is obeyed in the range of 0~10μg Cd(Ⅰ)/25ml. Satisfactory results have been achieved in applying the method to spectrophotometric determination of trace cadmium in industrial waste water and standard water samples.
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