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《Chinese Journal of Analytical Chemistry》 1993-11
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Spectrofluorimetric Determination of Silver Using 3,5-Dibromosalicylaldehyde-thiosemicarbazone

Yang Changhui, Yang Zhibin , Zhang Chunming (Department of Chemistry, Jiangxi University, Nanchang 330047)  
3,5-Dibromosalicylaldehyde-thiosemicarbazone (3,5-DBSTS) is described as a new fluorimetric reagent for the determination of trace silver. 3,5-DBSTS is synthesized by 3,5-dibromosalicylaldehyde and thiosemicarbazide. Ag+ reacts with 3,5-DBSTS to form a complex which causes the fluorescence to quench, the extent of fluorescence quenching is linear over 0. 04-25μg/25ml for silver. The optimum pH range for the determination of fluorescence is 8-9 in buffer solution of borax-nitric acid. The molar ratio of complex is established to be 1 : 1. The fluorescence measurements are made at excitation and emission wave length of 385 and 500nm,respectively, using EDTA as masking agent, the method is free from interference of 14 cations investigated, and has been used to determine the trace silver in anode slime with satisfactory results.
【Fund】: 江西省自然科学基金
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1 ZHANG Bing1,WU Bowan1,LIU Jianning1,YU Xinqiao1,ZHAO Jianshe2(1.Dept.Chem., Qingyang Normal College, Qingyang 745000, Gansu,China;2.Dept.Chem., Northwest Univ.,Xi'an 710069,Shaanxi,China);Synthesis of 2,4-dihydroxyacetophenone Schiff bases[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2003-01
2 LI Hui-cheng,LIU Jian-ning,WU Bo-wan(Department of Chemistry,Longdong University,Qingyang 745000,Gansu,China);Synthesis of 2-hydroxyacetophenone-2-formicanil and its application[J];Journal of Baoji University of Arts and Sciences(Natural Science Edition);2007-01
3 ZHANG Mei-li(College of Chemistry and Chemical Engineering,Yan'an University,Yan'an 716000,Shaanxi,China);Synthesis of N,N′-bis(x-methoxy salicyl aminal ethylene) oxalamide[J];Journal of Baoji University of Arts and Sciences(Natural Science Edition);2008-03
4 Pan Zuting, Zhang Tao, Xu Mianyi (Chemistry Department, Wuhan University, Wuhan 430072);Determination of Trace Silver by Fluorescence Quenching With meso-Tetra(4-pyridyl )porphyrin and Its Application[J];Chinese Journal of Analytieal Chemistry;1997-11
5 Jiang Chongqiu, Liu Guangjing, Tang Bo, Liang Fangzhen, Wang Wei (Department of Chemistry, Shandong Normal University, Jinan, 250014);Synthesis and Studies on Fluorimetric Quenching Reaction Between Beryllium and a New Spectrofluorimetric Reagent N 2 Thiazol Salicylimino Schiffs Base[J];JOURNAL OF ANALYTICAL SCIENCE;1998-01
6 KANG Xin huang (Department of Basis, Zhanjiang Ocean University, Zhanjiang ,524088),Fenxi Shiyanshi,2001,20(2):49~51;Synthesis of New Schiff′s Base SABAQ and Its Application in Fluorimetric Determination of Trace Amounts of Zinc in Crops[J];Analytical Laboratory;2001-02
7 Liu Changsong;WeiYansheng and Jin Weijun ( Department of Chem-istry, Shanxi University, Taiyuan 030006);Luminescence Analysls[J];ANALYTICAL LABORATORY;1995-04
8 ZHANG Ming,CHEN Zhen-feng,LIANG Hong,SHI Shao-ming (Department of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin 541004,China);PROGRESS IN THE STUDIES OF SEVERAL KINDS OF N-2-THIAZOLE SCHIFF BASES AND THEIR COMPLEXES[J];Journal of Guangxi Normal University(Natural Science);2002-03
9 WANG Qing-Hua WENG Wen ZHENG Zhao-Qi(Department of Chemistry,Zhangzhou Normal University,Zhangzhou,Fujian 363000,P.R.China);Spectrophotometric Determination of Trace Copper Based on a Schiff-Base Derived from 4-Aminoantipyrine and Salicylic Aldehyde[J];Chinese Journal of Spectroscopy Laboratory;2008-02
10 Liang,FangZhenJiang,ChongQiuHuang,RuQi (Shandong Key Laboratory of Organic Synthesis,Department of Chemistry,Shandong Normal University,Jinan,250014);Synthesis and Fluorogenic Property of New Fluorogenic ReagentN2thiazol Salicyldimino Schiff Bases[J];CHINESE JOURNAL OF SYNTHETIC CHEMISTRY;1999-02
Chinese Journal Full-text Database 10 Hits
1 Qian Xihua Zhu Rongxing Tang Xuhui (The Changzheu Building Materials Factory);THE APPLICATION OF UNIFORM DESIGN METHOD FOR SYNTHESIZING UNSATURATED POLYESTER RESIN IN LABORATORY[J];Engineering Plastics Application;1988-03
2 Du Qingbo, Li Yadong, Guo Weimin, Zhang Hualin (Qiemical Engineering Department, Zhengzhou Institute of Light Industry 450002)Wang Jun (Department of Physics of Zhengzhou University 450052);INFLUENCE OF THE COUPLING AGENT ON THE STRUCTURE AND PROPERTIES OF THE COMPOSITE COATINGS BY FLAME SPRAYING[J];Engineering Plastics Application;1998-10
3 Xu Qianghua Zhou Shiping (Nantong Life-Organic Chemistry Laboratory, Jiangsu Nantong 226007);Extraction and Mensuration of Bilirubin[J];Anhui Chemical Industry;2005-04
4 WU Zhi-chuan; MA Huai-zhu ( Dept. of Bioch. Engn.,Anhui Institute of Mechanical & Electrical Engineering, Wuhu 241000, China; Inst. of Org. Chem., Anhui Normal University, Wuhu 241000, China);Synthesis and characterization of rare earth organometallic complexes involving cyclopentadienyl and diaminothiadiazole ligands[J];JOURNAL OF ANHUI INSTITUTE OF MECHANICAL AND ELECTRICAL ENGINEERING;2000-03
5 WU Zhi chuan, CHENG Guang yue, LI Shi chuan (Dept. of Bioch. Engn., Anhui Institute of Mechanical& Electrical Engineering, Wuhu 241000, China);Synthesis and characterization of p- Ferrocenyl Benzene Monocarboxylic Acid[J];Journal of Anhui Institute of Mechanical and Electrical Engineering;2001-03
6 HUANG Xiao-hua1,WANG Xiu-ran2 (1.Dept.of Text.&Garm.,Anhui Insti tute of Mechanical and Electrical Engineering;Wuhu 241000,China;2.Res.Ins.of Qrg.Chem.,Anhui Norm al University,Wuhu 241000,China);Synthesis and characterization of o rganoindium complexex involving ethyl andβ-diketonate ligands[J];Journal of Anhui Institute of Mechanical and Electrical Engineering;2001-04
7 WU Jia-di et al (Biological Technology College of Shenyang Agriculture University,Shenyang,Liaoning 110161);Studies on the Enzyme Hydrolysis of Soluble Polysaccharide from Momordica Charantia[J];Journal of Anhui Agricultural Sciences;2005-01
8 Wen yong Li, (Department of Chemistry, Fuyang Normal College);Determination of gibberellic acid with a modified ultraviolet method[J];AMINO ACIDS & BIOTIC RESOURCES;1999-01
9 Si Wenhui(Basic Course Drpartment);Discussion about Significant Digits of "One-Ten Thousandth/Eleitricity-Light Balance[J];JOURNAL OF ANHUI AGROTECHNICAL;1995-01
10 ZHANG Xiu-hong,LIAO Qing,CHEN Xiong,LI Qing(Department of Materials Science and Engineering,Beijing Institute Of Clothing Technology Beijing 100029,China);Synthesis of N,N-dialkylurea and Its Structure Analysis[J];;2006-04
Chinese Journal Full-text Database 10 Hits
1 Ma Wen Xie Fuxing Wang Yongtao Tian Yupeng Li Shengli (Department of Chemistry Anhui University Hefei 230039);Antibacterial Activity of a Novel Schiff Base and its Comples of Cu(Ⅱ)[J];JOURNAL OF ANHUI UNIVERSITY(NATURAL SCIENCES);1999-01
2 ZHU Yan wu, ZHOU Yun you (College of Chemistry and Material Science, Anhui Normal University, Wuhu, Anhui, 241000, China);SYNTHESIS BY MICROWAVE AND FLUORESCENT PROPERTY OF 9-METHYLAGRIDINE[J];Journal of Anhui Normal University(Natural Science);2001-02
3 ZHANG Ming-cui, SHANG Yong-jia, ZHU Yin-gui, WANG Lun (College of Chemistry and Materials Science , Anhui Normal University,Wuhu 241000, China);SYNTHESIS AND FLUORESCENCE PROPERTY OF A NEW FLUORESCENT REAGENT 5-(4-CHLOROPHENYLAZO)-8- SALICYLIDENEAMINOQUINOLINE[J];Journal of Anhui Normal University(Natural Science);2001-04
4 Wang Zhongyi; Shi Haijian; Shi Haoxin;Yang Zhoushen;Zheng Erhua(Department of Chemistry)(Test and Analysis Center);Study on Synthesis of 5 (4′ Hdo9eno 2′ Carboxy phenylazo) Rhodanine and Their Fluorescence.  ̄1H NMR. MS.[J];Journal of Anhui Normal University(Natural Science);1994-03
5 Wang Guangbin(Department of C heniistry, Xianyang Teachers College);Antibacterial Activity of Cu (Ⅱ)、Zn (Ⅱ) Complexes with Schiff BaSe of DL-Methionine[J];;1994-01
6 Liu Xingrong; Liu Xiaojing; Li Mingxia; Li Jing(Department Pharmacy, Shandong Medical University , Jinan, 250012);Synthesis and Antibacterial Activity of Some Amino Acid Schiff Bases[J];AMINO ACIDS & BIOTIC RESOURCES;1996-01
7 Zhu Zhenfu Li Zhichang Institute of Applied Chemistry, Southwest China Normal University, Chonqing 630715;Progress in the Studies on Metal Complexes of Amino Acid Schiff Base[J];AMINO ACIDS & BIOTIC RESOURCES;1997-01
8 Xi Xiaolan Li Zhichang (Institute of Applied Chemistry, Southwest China Normal University, Chongqing 400715);Progress in the Studies on Antibacterial and Antitumor Acivitles of Amino Acid Schiff Base and its Metal Complexes[J];AMINO ACIDS & BIOTIC RESOURCES;1998-04
9 NING Bin ke, YANG Zheng quan, LIU Rong, WANG Yuan, PAN Qing , HU Rong Zu (Xi′an Modern Chemistry Research Institute, Xi′an 710065, China);A Study on the Denitration Kinetics of Highly Nitrated Nitrocellulose[J];CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS;2000-01
10 Feng Jianzhang, Zhang baexin Department of Chemistry;Spectrophotometric Determination of Micro Amounts of Iron in Natural Water, Hair and Blood[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1983-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LU Yu-ting,ZHANG Jie-xin,YN Da-wei(College of Chemistry&Chemical Engineering,Shaanxi University of Science &Technology,Xi'an 710021,China);Progress on the Capabilities of Amino Acid Schiff Base and ts Metal Complexes[J];Amino Acids & Biotic Resources;2008-03
2 LI Hui-cheng,LIU Jian-ning,WU Bo-wan(Department of Chemistry,Longdong University,Qingyang 745000,Gansu,China);Synthesis of 2-hydroxyacetophenone-2-formicanil and its application[J];Journal of Baoji University of Arts and Sciences(Natural Science Edition);2007-01
3 LI Ling Chen Liangbi(Chemistry and Environmental Engineering Department of Nanping Teachers College, Wuyishan,Fujian 354300,China);Determination of Micro-Aluminum in Jiuqu Stream by Molecular Fluorescence Spectrometry[J];Fujian Analysis & Testing;2007-02
4 WangRong, ZouShiying (Material and Chemical Engineering Department, Sichuan University of Science and Engineering,Zigong,Sicuang 643000,China );Spectrophotometric Determination of Zinc in Milk with 4-(2-Pyridy Lazo)-Resorcinol[J];Fujian Analysis & Testing;2008-04
5 KANG Xin huang, DENG Chun mei (Department of Basis ,Zhanjiang Ocean University, Zhanjiang 524088, China);Synthesis of New Shiff's Base DBSAQ and Fluorimetric Determination of Trace Aluminum(Ⅲ) in Crops[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;2000-03
6 Zhou Yanxiu, Zhu Guoyi. (National Analytical Research Center of Electrochemistry and Spectroscopy, Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Advance of Flow Injection-Chemiluminescence Detection[J];Chinese Journal of Analytieal Chemistry;1997-02
7 Liu Jiaming , Yang Tianlong, Zhu Guohui (Department of Chemistry, Zhangzhou Teachers College, Zhangzhou 363000) Fu Yan, Li Longdi (Department of Chemistry ,Tsinghua University, Beijing 100084);Determination of Trace Silver by Solid Surface Room Temperature Phosphorimetry[J];Chinese Journal of Analytical Chemistry;2003-06
8 Wei Danyi * (Department of Chemistry, Ningbo University, Ningbo, 315211) Qi Wenbin (Department of Enviromental Science, Hangzhou University, Hangzhou, 310028);The Comparative Studies on the Effect of Cyclodextrin and β Cyclodextrin Derivatives on Color and Fluorescence Reaction[J];JOURNAL OF ANALYTICAL SCIENCE;1999-05
9 DONG Hui ru (Beijing University of Chemical Technology, Beijing 100029),Fenxi Shiyanshi,1999,19(1):77~92;Analysis of the Chemical Industry, Petrochemical Industry Products and Silicate[J];ANALYTICAL LABORATORY;2000-01
10 ZHANG Zhujun, LI Baoxin and ZHENG Xingwang (School of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062);Luminescence Analysis[J];Analytical Laboratory;2003-04
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