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《Chinese Journal of Analytieal Chemistry》 1994-06
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Effect of β-Cyclodextrin on Color Reactions Mechanism of the Synergistic Effect With Ionic Surfactant

Li Yimin(Department of Chemistry, Shaoxing Teachers' College)Qi Wenbin, Chen Yuhong, Huang Zhiming, Cai Yougen(Department of Chemistry, Hangzhou University, Hangzhou 310028)  
The mechanism of the synergistic sensitizing effect on the color reactions by β-cy-clodextrin (β-CD) with surfactants was studied with respect to the essence of inclusion complex formation by β-CD and the increase of the inclusion constant with ionic surfactant. It indicated that the surfactant (SF) included by β-CD producing SF-β-CD inclusion complex and then the enhancement of the effect of SF-β-CD on the color reagent and its corresponding colored complex are the main factors for the synergistic effect. However,the stability of the colored complex and the effect of SF-β-CD on the value of the reagent blank should also considered. An approximate estimating method for the synergistic tendency of the same color reaction by different ionic surfactants with β-CD was also proposed.
【Fund】: 浙江省分析测试基金资助项目
【CateGory Index】: O657.3
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