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《Chinese Journal of Analytieal Chemistry》 1995-05
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Synthesis of 3,5-Dibromosalicylidene-isoniazid and Its Fluorescence Reaction With Scandium

Yang Zhibin, Fan Wenjuan, Luo Lin (Department of Chemistry, Nanchang University, Nanchang 330047)  
A fluorescent reagent, 3, 5-dibromosalicylidene-isoniazid (DBSIN) was synthesized, and characterized by IR and UV spectra. Scandium(III) reacts with DBSIN to form a fluorescent complex, while the other rare earth elements do not react. The fluorescence excitation and emission wavelengths of the complex are 335. 4 and 510 nm, respectively. The molar ratio of Sc : DBSIN is found to be 1 : 1. The optimum pH range for the determination of scandium is 4. 7-5. 5 (in buffer solution of sodium acetate-acetic acid). The proposed method has been used to determine the micro amounts of scandium in mixed oxide of rare earth elements with satisfactory results.
【Fund】: 南昌大学基础理论基金
【CateGory Index】: O657.3
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