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《Chinese Journal of Analytieal Chemistry》 1995-11
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Highly Sensitive Colour Reaction of Cadmium ( Ⅱ ) With Bromide-Rhodamine B——Centrifugation-Spectrophotometric Determination of Cadmium

Wu Shaozu , Fang Wenhuan (Department of Applied Chemistry, Huaqiao University, Quanzhou 362011)  
A highly sensitive centrifugation-spectrophotometric method was developed for the determination of trace cadmium. The complex in the title system shows a wavelength of absorption peak at 560 nm and a molar absorptivity of 5. 06 * 108 L mol-1 cm-1. Beer's law is obeyed in the range of 0. 10*10-2-1. 0*10-2 ug/10 mL for cadmium. The method has been applied to the determination of cadmium in the serum and water. The reaction mechanism was also discussed.
【Key Words】: Cadmium spectrophotometry rhodamine B bromide
【CateGory Index】: O657.3
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