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《Chinese Journal of Analytical Chemistry》 1999-06
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Catalytic Spectrophotometric Determiantion of Trace Chromium(Ⅵ)Using Cetyltrimethylammonium Bromide as Sensitizer

Wu Hezhou, Qiu Caiying, Zheng Zhaosheng ( Department of Chemistry, Fuzhou University, Fuzhou 350002)  
A new catalytic spectrophotometric method for the determination of trace Cr(Ⅵ) has beendeveloped. The method is based on the catalytic effect of Cr(Ⅵ) on the discoloring reaction of alizarinred oxidized with hydrogen peroxide. The enchancing of discoloring reaction is remarkable in the presenceof cetyltrimethylammonium bromide (CTMAB). Because of the addition of CTMAB, the sensitivity increases 4.8 times. The linear range of determination is 0.010 ~ 0.090 rng/L, the detection limit is 8.9×10-4 mg/L, and the relative standard deviation is 1.9% (n = 9), The method has been used to thedetermiantion of Cr(Ⅵ) in waste water.
【Fund】: 福建省自然科学基金资助课题
【CateGory Index】: O657.3
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