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《Chinese Journal of Analytical Chemistry》 1999-10
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Catalytic Spectrophotometric Determination of Trace Barium Based on the Decoloration Reaction of Erichrome Black T and Dodecylbenzene Sulfonic Sodium

Liu Jiaming (Department of Chemistry, Zhangzhou Normal College, Zhangzhou 363000)Ma Tongsen (Chemistry and Chemical Engineering College, He'nan University, Kaifeng 475001)  
Barium ion can catalyze the decolorization reaction of Erichrome Black T and dodecylbenzene solfonic sodium in a pH 5 of weak acid medium. The condition of kinetics has been studied in detail andthe optimum condition of catalytic kinetic determination of barium was established. The apparent molarabsorptivity . The equation of calibration curve is log+0.008704CBa3+(Ug/L) with the linear range of 0~16μg/L( r= 0. 9991) , the detection limit forbarium is 4.0×10-11 g/mL. This catalytic reaction is a first order reaction and its activation energy E is142.53 kJ/mol, rate constant K is 3.15×10-2/s. The method has been applied to the determination oftrace Ba( E ) in water samples, the results were in agreement with those given by AAS method.
【CateGory Index】: O657.3
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China Proceedings of conference Full-text Database 2 Hits
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2 Wang Zhaoxiang,Mo Yujun,Ma Jiming~* and Liu Yulong Institute of Physics,Chinese Academy of Sciences *Chemistry Department of Peking University.;A SERS COMPARISON OF CTAB ABSORBED ON SILVER MIRROR AND ON POLISHED COPPER SUBSTRATES[A];[C];1991
Chinese Journal Full-text Database 10 Hits
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2 CHEN Hao-Wen (The First Institute of Oceanography, SOA, Qingdao 266003, China);Monitoring the Content of Airborne Microbes Over the Chinese Great Wall Station,Antarctica[J];JOURNAL OF GLACIOLGY AND GEOCRYOLOGY;1998-04
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8 Zhu Quanzhi(South China Institute for Environmental Sciences,NEPA,Guangzhou 510655);ARS-300A——A New Automatic Acid Rain Sampler[J];CHONGQING ENVIRONMENTAL SCIENCE;1998-01
9 Zheng Huaili,Zhao Huiming(Departmet of Fundamental Science,Chongqing Jianzhu University,Chongqing 400045)Zhang Yuqi(Analytical and Testing Center,Chongqing Jianzhu University,Chongqing,400045);Rapid Determination of Metal Ingredient in Sewage Sludges[J];CHONGQING ENVIRONMENTAL SCIENCE;1998-04
10 Author JiHaoyu,PengFengcui(PangzhihuaMunicipalEnvironmentalMonitoringStation,Pangzhihua617000) T5HZ;SelectingDi lutionRateinBOD5DetermineofWasteWaterofHospital[J];CHONGQING ENVIRONMENTAL SCIENCE;1999-02
【Secondary References】
Chinese Journal Full-text Database 4 Hits
1 DAN De-zhong~,SHEN Lu and ZHU Yan-tao(Department of Environmental Science and Engineering,Sichuan University,Chengdu 610065);Analysis of environmental samples[J];Chinese Journal of Analysis Laboratory;2006-06
2 WU Jiansheng 1,2,SONG Jing 1,2,ZHENG Maokun 2,Xie Jing 1,LI Junjie 1,2,HUANG Xiulan 1 (1.Key Laboratory for Urban Habitat Environmental Science and Technology,School of Urban Planning and Design,Shenzhen Graduate School of Peking University,Shenzhen Guangdong 518055,China;2.Key Laboratory for Earth Surface Processes,Ministry of Education,College of Urban and Environmental Sciences,Peking University,Beijing 100871,China);Review of methods for monitoring soil heavy metal concentrations[J];Journal of Northeast Agricultural University;2011-05
3 WANG Yi ming, WANG Xiao hua, WANG Jian (Zhejiang Provincial Zhoushan Marine Ecological Environmental Monitoring Station, Zhoushan 316000, China) GUO Yuan ming (Zhejiang Provincial Fishery Research Institute);AFS DETERMINATION OF TRACE AMOUNTS OF MERCURY IN MARINE SEDIMENTS[J];Physical Testing and Chemical Analysis Part B Chemical Analysis;2003-11
4 ZHUXia-shi 1,2 ,JIANG Zu-cheng 2 ,HUBin 2 (1.Department of Chemistry,Yangzhou University,Yangzhou225002,China; 2.Department of Chemistry,Wuhan University,Wuhan430072,China);The Analysis of Chromium Speciation by Separation/Preconcentration Atomic Spectrometry[J];Journal of Instrumental Analysis;2005-04
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
2 Sun Peipei, Wu Bincai, Liu Hengchuan (Department of Chemistry, East China Normal University, Shanghai 200062);Synthesis of Two New Trizenediyl Color Reagents and Their Color Reactions With Cadmium[J];Chinese Journal of Analytieal Chemistry;1994-05
3 Niu jianjun,Wang Bingwu (Changchun Institute of Applied Chemistry ,Chinese Academy oj Sciences, Changchun 130022);Hydride Generation-Spectrophotometry[J];Chinese Journal of Analytieal Chemistry;1994-05
4 Li Yimin(Department of Chemistry, Shaoxing Teachers' College)Qi Wenbin, Chen Yuhong, Huang Zhiming, Cai Yougen(Department of Chemistry, Hangzhou University, Hangzhou 310028);Effect of β-Cyclodextrin on Color Reactions Mechanism of the Synergistic Effect With Ionic Surfactant[J];Chinese Journal of Analytieal Chemistry;1994-06
5 Wang Zunben , Zheng Zhuzi, Jin Min (Department of Chemistry, Institute of Analytical Chemistry, Xiamen University, Xiamen 361005);Determination of Iron in Drinking Water and Medicine by First Derivative Stop-flow Method[J];Chinese Journal of Analytieal Chemistry;1994-07
6 Zhang Xiaosong , Lin Changshan (Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026);Application of Azo Reagents in High-performance Liquid Chromatographic Determination of Metal Ions[J];Chinese Journal of Analytical Chemistry;1994-08
7 Bai Yuwei (Department of Chemistry, Xianyang Teachers College, Xi'anyang 712000) Lu Jiuru (Department of Chemistry, Shaanxi Normal University, Xian 710062);Spectrophotometric Determination of Trace Gold by On-line Separation[J];Chinese Journal of Analytical Chemistry;1994-09
8 Chen Jianrong , Wu Xiangmei, Yuan Weiju (Department of Chemistry, Zhejiang Normal University, Jinhua 321004) Tang Fulong (Department of Chemistry, Hangzhou University);Color Reaction of Iron(Ⅱ) With l-(5-Bromo-2-pyridylazo)-2- naphthol-6-sulphonic Acid and Its Application[J];Chinese Journal of Analytical Chemistry;1994-09
9 Pan Zhongxiao,Wang Shuanhu, Chen Wei, Zhang Maosen (Departmet of Modern Chemistry, University of Science and Technology of China, Hefei 230026);Study on the Multicomponent Determination by Artificial Neural Networks-Ultraviolet Spectrophotometry[J];Chinese Journal of Analytical Chemistry;1994-09
10 Ma Qinghe, Song Tianle, Cai Xinhua, Meng Lingpeng, Zheng Shijun (Department of Chemistry, Hebei Teachers' College, Shijiazhuang 050091);Application of Quantum Chemistry to the Researches on the Reactivities of Analytical Reagents[J];Chinese Journal of Analytical Chemistry;1994-09
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