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The Structure Characterization for Molecule Imprinting polymers and the Thermodynamic Study in the Chiral Separation Process

Meng Zihui. (Institute of Pharmacology and Toxicology, Academy of Military Medical Sciences, Beijing 100850) Zhou Liangmo, Wang Jinfang, Wang Qinghai, Zhu Daoqian (Dalian Institute of Chemical and Physics, Chinese Academy of Sciences, Dalian 116012)  
The thermal stability and pore structure of a series of molecule imprinted polymers were investigated. The relationship between the pore structure and chiral selectivity was discussed. The thermodynamic parameters in the chiral separation process were calculated. It was found that the chiral separation process on molecule imprinting chiral stationary phase was an enthalpy controlling process, and the thermodynamic parameters were in relationship with tile structure of print molecule.
【Fund】: 国家自然科学基金资助项目!(No.29775025)。
【CateGory Index】: O631
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